(反式)-1,1'-(1,2-环丙烷二基)二苯合成路线 （共 61 条）
反应条件
1.1: diethylzinc; trifluoroacetic acid / dichloromethane / 1.33 h / 5 °C
1.2: 5 h / 5 - 20 °C
2.1: N,N,N',N'-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a;2',1'-c][1,4] diazepine-2,12-diamine / N,N-dimethyl-formamide / 24 h / 20 °C / Inert atmosphere; UV-irradiation
3.1: N,N,N',N'-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a;2',1'-c][1,4] diazepine-2,12-diamine / N,N-dimethyl-formamide / 24 h / 20 °C / Inert atmosphere; UV-irradiation
View Scheme
参考文献
Cahard, Elise; Schoenebeck, Franziska; Garnier, Jean; Cutulic, Sylvain P. Y.; Zhou, Shengze; Murphy, John A.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 15 p. 3673 - 3676
反应条件
in cyclohexane
Isomerization; Cyclization; UV-irradiation; Title compound not separated from byproducts;
参考文献
Jimenez; Miranda; Tormos
Chemical Communications, 2000 , # 23 p. 2341 - 2342
反应条件
in various solvent(s)
T=-23.16°C; Zimmermann rearrangement; KineticsQuantum yield; Further Variations:Temperatures;
参考文献
Lewis; Zuo; Kalgutkar; Wagner-Brennan; Miranda; Font-Sanchis; Perez-Prieto
Journal of the American Chemical Society, 2001 , vol. 123, # 48 p. 11883 - 11889
反应条件
ClFeTPP; N-benzyl-N,N,N-triethylammonium chloride in toluene
T=40°C; Product distribution; Further Variations:SolventsTemperaturesReagents;
参考文献
Aggarwal, Varinder K.; De Vicente, Javier; Bonnert, Roger V.
Organic Letters, 2001 , vol. 3, # 17 p. 2785 - 2788
反应条件
1.1: diethylzinc; trifluoroacetic acid / dichloromethane / 1.33 h / 5 °C
1.2: 38 h / 5 - 20 °C
2.1: N,N,N',N'-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a;2',1'-c][1,4] diazepine-2,12-diamine / N,N-dimethyl-formamide / 11 h / 20 °C / Inert atmosphere; UV-irradiation
View Scheme
参考文献
Cahard, Elise; Schoenebeck, Franziska; Garnier, Jean; Cutulic, Sylvain P. Y.; Zhou, Shengze; Murphy, John A.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 15 p. 3673 - 3676
反应条件
potassium-sodium in tetrahydrofuran
T=0°C; 4 h; Product distributionMechanism;
参考文献
Boche, Gernot; Schneider, Dieter R.; Wernicke, Klaus
Tetrahedron Letters, 1984 , vol. 25, # 28 p. 2961 - 2964
反应条件
sulfur dioxide; trifluoroacetic acid
T=20°C; 5 h; sealed tube; Yield given;
参考文献
Bondarenko, O. B.; Buevich, A. V.; Voevodskaya, T. I.; Saginova, L. G.; Shabarov, Yu. S.
Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, # 9 p. 1746 - 1753
Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 9 p. 1937 - 1944
参考文献
Fox, Marye Anne; Chen, Chia-Chung; Campbell, Kay A.
Journal of Organic Chemistry, 1983 , vol. 48, # 3 p. 321 - 326
反应条件
in cyclohexane
Irradiation; Yields of byproduct given;
参考文献
Miranda, Miguel A.; Perez-Prieto, Julia; Font-Sanchis, Enrique; Konya, Klara; Scaiano
Journal of Physical Chemistry A, 1998 , vol. 102, # 48 p. 9975 - 9977
反应条件
benzylidene(pentacarbonyl)tungsten in dichloromethane; pentane
T=-74°C; var. temp., olefin and complexe conc.; other alkenes and var subst. benzylidene(pentacarbonyl)tungsten and chromium complexes; Product distributionMechanism;
参考文献
Fisher, Helmut; Jaeger, Monika
Journal of Organometallic Chemistry, 1993 , vol. 456, # 2 p. 205 - 212
