三(1,2-苯二醇酸根-O,O')锗酸二钾合成路线 （共 20 条）
反应条件
in diethyl ether (N2); added dropwise a soln. of C2H5MgBr to a suspn. of Ge-compound at room temp.; stirred for 30 min; hydrolyzed; extracted with ether; washed with water; dried over MgSO4; evapd.;
参考文献
Cerveau, G.; Chuit, C.; Corriu, R. J. P.; Reye, C.
Organometallics, 1988 , vol. 7, p. 786 - 787
反应条件
phenyl-magnesium bromide in diethyl ether (N2); added dropwise C6H5MgBr to a suspn. of Ge-compound at room temp.; stirred for 15 min; hydrolyzed; pptd.; filtered; extracted with CHCl3; washed with water; dried over MgSO4; evapd.; recrystd. from toluene;
参考文献
Organometallics, , vol. 10, p. 1510 - 1515
反应条件
magnesium in tetrahydrofuran (N2); heated a suspn. of Mg and Ge-compound under stirring to 50°C; added dropwise a soln. of bromo benzene over 1.5 h; refluxed for 2 h; cooled; added ether; hydrolyzed; pptd.; filtered; washed with water, acetone and ether; dried; extracted with ether; washed with water; evapd.; recrystd. from toluene; GC;
参考文献
Organometallics, , vol. 10, p. 1510 - 1515
反应条件
magnesium; ethylene dibromide; phenyl-magnesium bromide in diethyl ether (N2); added dropwise a soln. of 1,2-dibromoethane to suspn. of Mg; stirred for 2,5 h; added a suspn. of Ge-compound and a soln. of C6H5MgBr over a period of 45 min at 20°C; stirred for 1 h at 20°C; added LiAlH4; refluxed for 1 h; cooled; added ethane; evapd.; distd.; GC;
参考文献
Organometallics, , vol. 10, p. 1510 - 1515
反应条件
hydrogenchloride; magnesium in diethyl ether; water (N2); added dropwise a mixture of 1,2-dibromoethane and C6H5Br to a ice-cooled suspn. of Mg over 6 h; added to a suspn. of Ge-compound at 0°C; hydrolyzed with aq. HCl; treated with pentane; filtered; evapd.; recrystd. from ethanol;
参考文献
Cerveau, G.; Chuit, C.; Corriu, J. P.; Reye, C.
Organometallics, 1991 , vol. 10, p. 1510 - 1515
反应条件
1-bromo-butane; magnesium in tetrahydrofuran (N2); heated a suspn. of Mg and Ge-compound under stirring to 50-55°C; added dropwise a soln. of n-butyl bromide; refluxed under stirring for 2 h; cooled; added ether; evapd.; distd.;
参考文献
Cerveau, G.; Chuit, C.; Corriu, J. P.; Reye, C.
Organometallics, 1991 , vol. 10, p. 1510 - 1515
反应条件
in diethyl ether (N2); added dropwise a soln. of C4H9MgBr to a suspn. of Ge-compound at room temp.; stirred for 30 min; hydrolyzed; extracted with ether; washed with water; dried over MgSO4; evapd.;
参考文献
Cerveau, G.; Chuit, C.; Corriu, R. J. P.; Reye, C.
Organometallics, 1988 , vol. 7, p. 786 - 787
反应条件
bis(cyclopentadienyl)titanium dichloride in diethyl ether dropwise addn. of EtMgBr at room temp. to suspn. of Ge comp. and Cp2TiCl2 in Et2O under N2, mixt. is heated to reflux for 4 h;
参考文献
Cerveau, G.; Chuit, C.; Corriu, R. J. P.; Reye, C.
Organometallics, 1988 , vol. 7, p. 786 - 787
反应条件
in tetrahydrofuran; diethyl ether (N2); added dropwise a soln. of C2H3MgBr to a suspn. of Ge-compound; stirred for 1 h at 45°C; hydrolyzed; extracted with ether; washed with water; dried over MgSO4; evapd.;
参考文献
Cerveau, G.; Chuit, C.; Corriu, J. P.; Reye, C.
Organometallics, 1991 , vol. 10, p. 1510 - 1515
反应条件
in diethyl ether
potassium tris(1,2-benzenediolato)germanate and 4 equiv 1-NpMgBr in Et2O at 35°C for 12 h;
参考文献
Cerveau, G.; Chuit, C.; Corriu, R. J. P.; Reye, C.
Organometallics, 1988 , vol. 7, p. 786 - 787
