2,6,6-三甲基-2-环己烯-1,4-二酮合成路线 (共 28 条)
反应条件
2,6-dimethyl-4-heptanone; oxygen; 1,4-diaza-bicyclo[2.2.2]octane T=40°C; 5 h;
参考文献
Daicel Chemical Industries, Ltd.
Patent: US6346651 B1, 2002 ;
Location in patent: Page column 15-17 ;
反应条件
tert.-butylhydroperoxide; cobalt(II) 2,4-pentanedionate in acetone T=28°C; 15 h; SolventConcentrationTemperature;
参考文献
Han, Xiaoqiang; Zhou, Ziyuan; Wan, Chuan; Xiao, Yumei; Qin, Zhaohai
Synthesis (Germany), 2013 , vol. 45, # 5 art. no. SS-2012-H0891-OP, p. 615 - 620
反应条件
caesium carbonate in acetonitrile T=20°C; 0.3 h;
参考文献
Carreno, M. Carmen; Perez-Gonzalez, Manuel; Ribagorda, Maria; Somoza, Alvaro; Urbano, Antonio
Chemical Communications, 2002 , # 24 p. 3052 - 3053
反应条件
MoO3 in hexane; toluene
反应条件
oxygen; triethylamine; iron tetrasulfophthalocyanine-TiO2 in dimethyl sulfoxide T=60°C; P=1500.12 Torr; 24 h;
参考文献
New Journal of Chemistry, , vol. 29, # 10 p. 1245 - 1248
反应条件
methanesulfonic acid; oxygen; molybdovanadophosphate on active carbon in toluene T=80°C; P=760 Torr; 20 h; regioselectivity of the aerobic oxidation, effect of the pore size of supports, or without support at various temperatures; Product distribution;
参考文献
Tetrahedron Letters, , vol. 38, # 32 p. 5659 - 5662
反应条件
potassium dichromate; air; phosphomolybdic acid; copper(II) sulfate T=90 - 95°C; 100 h;
参考文献
Yates, Peter; Burnell, D. Jean; Freer, Vernon J.; Sawyer, Jeffery F.
Canadian Journal of Chemistry, 1987 , vol. 65, p. 69 - 77
反应条件
2-hydroxy-1,3-isoindolinedione; oxygen; copper(II) sulfate in acetonitrile T=75°C; P=9000.9 Torr; 5 h; Autoclave;
参考文献
Bulletin of the Korean Chemical Society, , vol. 33, # 2 p. 459 - 463
反应条件
tBuOCrO3H in tert-butyl alcohol; benzene T=60°C;
参考文献
Australian Journal of Chemistry, , vol. 42, # 12 p. 2071 - 2084
参考文献
Helvetica Chimica Acta, , vol. 39, p. 2041,2046
Justus Liebigs Annalen der Chemie, , vol. 603, p. 129,137