(1Z,6Z)-环癸-1,6-二烯合成路线 （共 5 条）
反应条件
aluminum oxide; sodium in dichloromethane T=25°C; 12 h;
参考文献
Alvarez, Eleuterio; Diaz, Maria T.; Perez, Ricardo; Ravelo, Jose L.; Regueiro, Alicia; et al.
Journal of Organic Chemistry, 1994 , vol. 59, # 10 p. 2848 - 2876
反应条件
water; oxygen; copper(l) chloride; palladium dichloride in tetrahydrofuran T=60°C; Yield given. Yields of byproduct given;
参考文献
Dzehemileva, G. A.; Odinokov, V. N.; Dzhemilev, U. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1987 , vol. 36, # 1 p. 131 - 136
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1987 , # 1 p. 149 - 154
反应条件
1: 95 percent / diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 2: pyridine / 15 h / -10 °C 3: Zn, sodium iodide / bis-(2-methoxy-ethyl) ether / 1.5 h / Heating 4: 10percent aq. hydrochloric acid / acetone / 6 h / Ambient temperature View Scheme
参考文献
Odinokov, V. N.; Galeeva, R. I.; Sokol'skaya, O. V.; Dzhemilev, G. A.; Tolstikov, G. A.
Doklady Chemistry, 1985 , vol. 280, p. 28 - 30
Dokl. Akad. Nauk SSSR Ser. Khim., 1985 , vol. 280, # 3 p. 646 - 649
反应条件
1: 95 percent / diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 2: pyridine / 15 h / -10 °C 3: Zn, sodium iodide / bis-(2-methoxy-ethyl) ether / 1.5 h / Heating 4: 10percent aq. hydrochloric acid / acetone / 6 h / Ambient temperature 5: diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 6: 91 percent / pyridine / 24 h / Ambient temperature View Scheme
参考文献
Odinokov, V. N.; Galeeva, R. I.; Sokol'skaya, O. V.; Dzhemilev, G. A.; Tolstikov, G. A.
Doklady Chemistry, 1985 , vol. 280, p. 28 - 30
Dokl. Akad. Nauk SSSR Ser. Khim., 1985 , vol. 280, # 3 p. 646 - 649
反应条件
1: 95 percent / diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 2: pyridine / 15 h / -10 °C 3: Zn, sodium iodide / bis-(2-methoxy-ethyl) ether / 1.5 h / Heating 4: 10percent aq. hydrochloric acid / acetone / 6 h / Ambient temperature 5: diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C 6: 87 percent / trifenylphosphine, bromine / CCl4 / 1.) 15 deg C, 1h, 2.) RT, 15 h View Scheme
参考文献
Odinakov, V. N.; Ishmuratov, G. Yu.; Galeeva, R. I.; Sokol'skaya, O. V.; Sagitdinova, Kh. F.; Tolstikov, G. A.
Journal of Organic Chemistry USSR (English Translation), 1990 , vol. 26, # 1.1 p. 46 - 49
Zhurnal Organicheskoi Khimii, 1990 , vol. 26, # 1 p. 57 - 61
