4-氯-2,6-二甲基苯酚合成路线 (共 15 条)
反应条件
chlorine T=10°C; P=684 Torr; 0.666667 h; other time; other temp; other pressure; reactivity dependence on crystal structure; conversion; also in mixture with 3,5-dichlorophenol; Product distribution;
参考文献
Molecular Crystals and Liquid Crystals (1969-1991), , vol. 96, p. 57 - 70
反应条件
1,4-dioxane; copper oxide-chromium oxide T=170 - 180°C; Hydrogenation;
参考文献
Journal of Applied Chemistry, , vol. 5, p. 289,293
反应条件
in diethyl ether T=37°C; 24 h;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2617 - 2625
反应条件
in diethyl ether 18 h; Ambient temperature;
参考文献
Journal of Organic Chemistry, , vol. 51, # 2 p. 174 - 179
反应条件
in 1,4-dioxane; diethyl ether MechanismProduct distribution;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 23 p. 1617 - 1619
反应条件
oxygen in methanol T=21.85°C; Irradiation;
参考文献
Manet, Ilse; Monti, Sandra; Fagnoni, Maurizio; Protti, Stefano; Albini, Angelo
Chemistry - A European Journal, 2005 , vol. 11, # 1 p. 140 - 151
反应条件
Na2B4O7; 3,5-Dichlorobenzoquinone N-chloroimine in acetonitrile T=25°C; 0.333333 h; Title compound not separated from byproducts;
参考文献
Pallagi, Istvan; Toro, Andras; Farkas, Oedoen
Journal of Organic Chemistry, 1994 , vol. 59, # 22 p. 6543 - 6557
反应条件
Na2B4O7 in acetonitrile T=25°C; 0.333333 h; Title compound not separated from byproducts;
参考文献
Pallagi, Istvan; Toro, Andras; Farkas, Oedoen
Journal of Organic Chemistry, 1994 , vol. 59, # 22 p. 6543 - 6557
反应条件
manganese(IV) oxide in chloroform
参考文献
Tamburini, Sergio; Peruzzo, Valentina; Benetollo, Franco; Vigato, P. Alessandro
European Journal of Inorganic Chemistry, 2010 , # 12 p. 1853 - 1864
反应条件
1.1: potassium carbonate / acetone / 12 h / |Reflux 2.1: potassium hydroxide; potassium permanganate / water / 24 h / 80 °C / |Reflux 3.1: 2,2,6,6-tetramethylpiperidinyl-lithium / tetrahydrofuran / 4 h / -50 °C 3.2: 1 h / -50 - 20 °C / pH < 1 4.1: boron trichloride / dichloromethane / 2 h / 0 °C / |Inert atmosphere 5.1: titanium tetrachloride / dichloromethane / 22 h / -10 - 23 °C / |Inert atmosphere 6.1: silver nitrate; dihydrogen peroxide / acetonitrile / 15 h / 50 °C / |Reflux View Scheme
参考文献
Lenz, Cesar Antonio; Rychlik, Michael
Tetrahedron Letters, 2013 , vol. 54, # 8 p. 883 - 886