(E,E)-2,4-己二烯二酸二甲酯合成路线 （共 18 条）
反应条件
diisobutylaluminium hydride in dichloromethane T=-78°C; 0.5 h; Inert atmosphere;
参考文献
Huang, Yange; Fananas-Mastral, Martin; Minnaard, Adriaan J.; Feringa, Ben L.
Chemical Communications, 2013 , vol. 49, # 32 p. 3309 - 3311
参考文献
Treibs; Holbe
Chemische Berichte, 1952 , vol. 85, p. 608,612
反应条件
1: m-xylene / 48 h / 151 - 168 °C / 13446.2 Torr 2: hydrogen / palladium on activated charcoal / dichloromethane / 20 °C View Scheme
参考文献
AMYRIS, INC.; SCHWEITZER, Dirk, Ph.D.
Patent: WO2012/82725 A1, 2012 ;
反应条件
1: ammonia / ethanol; water / 336 h / 20 °C 2: hydrogen / Cr2Cu2O5 / tetrahydrofuran / 5 h / 300 °C / 27409.6 Torr View Scheme
参考文献
AMYRIS, INC.; BUI, Vu; FROST, John W.
Patent: WO2012/141993 A1, 2012 ;
反应条件
1: ammonia / ethanol; water / 336 h / 20 °C 2: hydrogen; ammonia / Cr2Cu2O5 / tetrahydrofuran / 5 h / 250 °C / 85331.7 Torr View Scheme
参考文献
AMYRIS, INC.; BUI, Vu; FROST, John W.
Patent: WO2012/141993 A1, 2012 ;
参考文献
Farmer; Duffin
Journal of the Chemical Society, 1927 , p. 410
反应条件
1: ammonia / ethanol; water / 336 h / 20 °C 2: hydrogen / Cr2Cu2O5 / tetrahydrofuran / 5 h / 300 °C / 27409.6 Torr View Scheme
参考文献
AMYRIS, INC.; BUI, Vu; FROST, John W.
Patent: WO2012/141993 A1, 2012 ;
反应条件
1: ammonia / ethanol; water / 336 h / 20 °C 2: hydrogen / Cr2Cu2O5 / tetrahydrofuran / 5 h / 300 °C / 27409.6 Torr 3: trichlorophosphate / Reflux View Scheme
反应条件
T=160°C; 19 h; Pressure tube;
参考文献
US2010/314243 A1, ;
Page/Page column 24 ;
反应条件
1: hydroquinone / m-xylene / 72 h / Inert atmosphere; Reflux 2: oxygen / platinum on carbon / m-xylene / 96 h / Reflux View Scheme
参考文献
AMYRIS, INC.; SCHWEITZER, Dirk, Ph.D.
Patent: WO2012/82725 A1, 2012 ;
