in solid solid-state synthesis from MnCl2 (10.3 mmol) and NaCH3COCHCOCH3 (19.7 mmol) by mechanical activation (vibrating quartz vessel for 2 h at 5 Hz); transferring product into dry box under inert atmosphere;; vac. sublimation (0.1 torr) at 150-200°C bath temp.;;
参考文献
Borisov, A. P.; Petrova, L. A.; Makhaev, V. D.
Journal of General Chemistry USSR (English Translation), 1992 , vol. 62, p. 10 - 12
Zhurnal Obshchei Khimii, 1992 , vol. 62, p. 15 - 17
in neat (no solvent, solid phase) mechanically activated solid state synthesis; eccentric-type ball mill, mixt. was treated for 30 min; mixt. was sepd. by vacuum sublimation on an oil bath at 120-160°Cand pressure of 13.3 Pa; elem. anal., XRD;
参考文献
Russian Journal of Inorganic Chemistry, , vol. 47, # 12 p. 1827 - 1832
Abeywickrema, Ramyani; Bennett, Martin A.; Cavell, Kingsley J.; Kony, Michael; Masters, Anthony F.; Webb, Alison G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1993 , # 1 p. 59 - 68
