3-((三甲基甲硅烷基)乙炔)苯胺合成路线 （共 8 条）
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide in diethylamine; N,N-dimethyl-formamide T=25°C; 5 h;
参考文献
Erdelyi; Gogoll
Journal of Organic Chemistry, 2001 , vol. 66, # 12 p. 4165 - 4169
反应条件
bis-triphenylphosphine-palladium(II) chloride; ammonium hydroxide; copper(l) iodide in tetrahydrofuran T=20°C; Sonogashira coupling; 3.5 h;
参考文献
Mohamed Ahmed, Mohamed S.; Mori, Atsunori
Tetrahedron, 2004 , vol. 60, # 44 p. 9977 - 9982
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triphenylphosphine in diethylamine; N,N-dimethyl-formamide T=120°C; Sonogashira reaction; 0.416667 h; microwave irradiation;
参考文献
Erdelyi; Gogoll
Journal of Organic Chemistry, 2001 , vol. 66, # 12 p. 4165 - 4169
反应条件
iron; acetic acid T=60 - 70°C; 12 h;
参考文献
Tomioka, Hideo; Sawai, Shinji
Organic and biomolecular chemistry, 2003 , vol. 1, # 24 p. 4441 - 4450
反应条件
1: 89 percent / Et3N; CuI / (PPh3)2PdCl2 / 24 h / 20 °C 2: Fe; AcOH / 12 h / 60 - 70 °C View Scheme
参考文献
Tomioka, Hideo; Sawai, Shinji
Organic and biomolecular chemistry, 2003 , vol. 1, # 24 p. 4441 - 4450
反应条件
1: 89 percent / Et3N; CuI / (PPh3)2PdCl2 / 24 h / 20 °C 2: Fe; AcOH / 12 h / 60 - 70 °C View Scheme
参考文献
Tomioka, Hideo; Sawai, Shinji
Organic and biomolecular chemistry, 2003 , vol. 1, # 24 p. 4441 - 4450
反应条件
potassium carbonate in tetrahydrofuran; methanol Inert atmosphere;
参考文献
Organometallics, , vol. 29, # 12 p. 2783 - 2788
反应条件
1: With hydrogenchloride; sodium nitrite
T=0°C; 1 h;
2: With sodium azide
T=0°C; 1 h; Further stages.;
参考文献
Tomioka, Hideo; Sawai, Shinji
Organic and biomolecular chemistry, 2003 , vol. 1, # 24 p. 4441 - 4450
