4-二(4-二甲基氨基苯基)膦基-N,N-二甲基苯胺合成路线 （共 11 条）
反应条件
phosphorus tribromide in benzene 1) 20 deg C, 2 d 2) 24h, reflux;
参考文献
Tolmachiev, A. A.; Ivonin, S. P.; Kharchenko, A. V.; Kozlov, E. S.
J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 5.2 p. 1193 - 1194,1057 - 1058
反应条件
phosphorus trichoride
参考文献
Tomaschewski
Journal fuer Praktische Chemie (Leipzig), 1966 , vol. <4>33, p. 168,174
反应条件
magnesium; phosphorus trichoride 1) THF, 2) THF, 0 deg C; Yield given. Multistep reaction;
参考文献
Brune, Hans Albert; Falck, Manfred; Hemmer, Reinhard; Schmidtberg, Guenter; Alt, Helmut G.
Chemische Berichte, 1984 , vol. 117, # 9 p. 2791 - 2802
参考文献
Schiemenz
Chemische Berichte, 1965 , vol. 98, p. 65,70
参考文献
Hanimann
Chemische Berichte, 1876 , vol. 9, p. 845
反应条件
T=130°C; nachfolgenden Behandeln mit verd.Natronlauge;
参考文献
Bourneuf
Bulletin de la Societe Chimique de France, 1923 , vol. <4>33, p. 1809
反应条件
Behandeln des Reaktionsprodukts mit verd.Natronlauge oder Sodaloesung;
参考文献
Raudnitz
Chemische Berichte, 1927 , vol. 60, p. 742
Chemische Berichte, 1928 , vol. 61, p. 246
参考文献
THE DOW CHEMICAL COMPANY
Patent: EP567677 A1, 1993 ;
反应条件
in tetrahydrofuran; dichloromethane
a soln. of HgCl2 in THF was added to a soln. of the ligand in CH2Cl2 (molar ratio HgCl2:P=1:2); the soln. was reduced in vol. and a small amt. of Et2O was added to ppt. the complex; recrystn. from CH2Cl2/Et2O; elem. anal.;
参考文献
Allman, Tim; Goel, Ram G.
Canadian Journal of Chemistry, 1984 , vol. 62, p. 615 - 620
