5,11,17,23-四硝基五环[19.3.1.13,7.19,13.115,19]二十八-1(25),3(28),4,6,9(27),10,12,15(26),16,18,21,23-十二烯-25,26,27,28-四醇合成路线 （共 4 条）
→
109051-62-95,11,17,23-四硝基五环[19.3.1.13,7.19,13.115,19]二十八-1(25),3(28),4,6,9(27),10,12,15(26),16,18,21,23-十二烯-25,26,27,28-四醇
反应条件
aluminium trichloride; potassium nitrate in acetonitrile T=0°C; 2 h;
参考文献
Zhang, Wen-Chun; Zheng, Yan-Song; Huang, Zhi-Tang
Synthetic Communications, 1997 , vol. 27, # 21 p. 3763 - 3767
→
109051-62-95,11,17,23-四硝基五环[19.3.1.13,7.19,13.115,19]二十八-1(25),3(28),4,6,9(27),10,12,15(26),16,18,21,23-十二烯-25,26,27,28-四醇
反应条件
nitric acid; acetic acid in dichloromethane 5 h;
参考文献
Kumar; Kurur; Chawla; Varadarajan
Synthetic Communications, 2001 , vol. 31, # 5 p. 775 - 779
→
109051-62-95,11,17,23-四硝基五环[19.3.1.13,7.19,13.115,19]二十八-1(25),3(28),4,6,9(27),10,12,15(26),16,18,21,23-十二烯-25,26,27,28-四醇
反应条件
hydrogenchloride 0.05 h; microwave irradiation;
参考文献
Agrawal; Thaker
Synthetic Communications, 2008 , vol. 38, # 14 p. 2437 - 2445
→
109051-62-95,11,17,23-四硝基五环[19.3.1.13,7.19,13.115,19]二十八-1(25),3(28),4,6,9(27),10,12,15(26),16,18,21,23-十二烯-25,26,27,28-四醇
反应条件
silver nitrate 1.) CHCl3, acetonitrile, 2.) reflux, 1.5 h.; Yield given. Multistep reaction;
参考文献
Zhang, Wen-Chun; Zheng, Yan-Song; Huang, Zhi-Tang
Synthetic Communications, 1997 , vol. 27, # 21 p. 3763 - 3767
