反应条件
1: sodium methoxide
2: 80 percent / H2, NEt3 / <Rh(1,5-cyclooctadiene)Cl>2, (4S,5S)-MOD-DIOP (12) / methanol / 40 h / 30 °C / 760 Torr
3: 1) aq. KOH, 2) CaCl2, NaBH4, KOH / 1) methanol, ice bath, 15 min, 2) ethanol, room temperature, 3 h
4: HCl / ethanol / 0.5 h
View Scheme
参考文献
Morimoto, Toshiaki; Chiba, Mitsuo; Achiwa, Kazuo
Tetrahedron, 1993 , vol. 49, # 9 p. 1793 - 1806