2-烯丙基-2-(2-丙炔-1-基)丙二酸二甲酯合成路线 （共 5 条）
反应条件
potassium carbonate in acetone 24 h; Heating;
参考文献
Trost; Shi
Journal of the American Chemical Society, 1993 , vol. 115, # 26 p. 12491 - 12509
反应条件
1: CH(CH2CH=CH2)(CO2Me)2 With sodium hydride in tetrahydrofuran; mineral oil T=0 - 20°C; Inert atmosphere; 2: propargyl bromide in tetrahydrofuran; mineral oil Inert atmosphere;
参考文献
Zhu, Shifa; Liang, Renxiao; Jiang, Huanfeng; Wu, Wanqing
Angewandte Chemie - International Edition, 2012 , vol. 51, # 43 p. 10861 - 10865
Angew. Chem., 2012 , vol. 124, # 43 p. 11019 - 11023
反应条件
1.1: sodium hydride / tetrahydrofuran; mineral oil / 0 - 20 °C / |Inert atmosphere 1.2: |Inert atmosphere 2.1: sodium hydride / tetrahydrofuran; mineral oil / 0 - 20 °C / |Inert atmosphere 2.2: |Inert atmosphere View Scheme
参考文献
Nagendiran, Anuja; Verho, Oscar; Haller, Clemence; Johnston, Eric V.; Baeckvall, Jan-E.
Journal of Organic Chemistry, 2014 , vol. 79, # 3 p. 1399 - 1405
反应条件
sodium periodate; ruthenium trichloride in tetrachloromethane; acetonitrile
参考文献
Bray, Katharine L.; Lloyd-Jones, Guy C.
European Journal of Organic Chemistry, 2001 , # 9 p. 1635 - 1642
反应条件
silver hexafluoroantimonate; C42H53AuClO4P in chloroform-d1
T=20°C; 5 h; Solvolysis; Overall yield = 95 percent;
参考文献
Malhotra, Deepika; Mashuta, Mark S.; Hammond, Gerald B.; Xu, Bo
Angewandte Chemie - International Edition, 2014 , vol. 53, # 17 p. 4456 - 4459
Angew. Chem., 2014 , vol. 126, # 17 p. 4545 - 4548,4
