lithium aluminium tetrahydride in diethyl ether prepared by LiAlH4 reduction of the corresponding trichlorogermane in Et2O; identified by NMR spectrum;
参考文献
Batchelor,R.J.; Birchall,T.
Journal of the American Chemical Society, 1983 , vol. 105, p. 3848
lithium aluminium tetrahydride in neat (no solvent) byproducts: N2, ClCH2CO2CH2CH3, C6H5COCH2CO2C2H5; 1 equiv of diazoester adding to an equimolar mixt. of Ge deriv. and PhCHO to result in an exothermic reaction with N2 evolution; supentatant treating with LiAlH4 in ether; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
lithium aluminium tetrahydride; acetaldehyde; triethylamine in diethyl ether byproducts: ethanol; 1 equiv of diazoester adding to a mixt. of equimolar amts. of Ge deriv.and acetaldehyde at 0°C then treating with an excess of LiAlH4 in Et2O; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
in neat (no solvent) byproducts: N2, ClCH2CO2CH2CH3; 1 equiv of diazoester adding slowly to an equimolar mixt. of Ge and Sn deriv. to result in exothermic reaction with N2 evolution; after 4 h at 20°C concg., diene ligand adding, heating in a sealed tube for 12h at 120°C; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
