azobis(isobutyronitrile) in neat (no solvent) High Pressure; (Ar); addn. of AIBN to stannane, addn. of GeCl4, heating to 150°Cfor 22 h in a sealed tube, cooling to room temp.; dissolving in CH2Cl2, vac. distn.;
AlCl3 in neat (no solvent) byproducts: CH3SiCl3; heated at 100°C for 2 h with removal of CH3SiCl3 (reflux ratio 15); heated at 100°C for 6 h and then at 120°C; AlCl3 filtered off; filtrate distd.; elem. anal.;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 53, p. 985 - 988
Zhurnal Obshchei Khimii, , vol. 53, p. 1111 - 1114
copper(l) iodide in toluene hydrogermane mixed with 6 equiv. of CuCl2 and CuI in toluene under reflux for 17 days; solvent evapd., distilled under reduced pressure;
aluminium trichloride in neat (no solvent) other Radiation; a mixt. of benzene, GeCl4 and powdered AlCl3 as catalyst is placed in aPyrex tube with N2 bubbling, 300-W microwave power is applied for 15 min, AlCl3 is added once more and the mixt. is refluxed for 2 h (Ar); mixt. is treated with POCl3 and filtered;
