(1R,2R)-反-1,2-环己二醇合成路线 （共 93 条）
反应条件
water T=25°C; 168 h; porcine liver esterase, ammonium sulfate, phosphate buffer 7.0 (maintained with aq. NaOH), or with hexane or toluene, other enzymes (lipase from Pseudomonas cepacia and others), other reaction times, relative rates, enantioselectivity; Product distributionEquilibrium constantMechanism;
参考文献
Journal of Organic Chemistry, , vol. 56, # 26 p. 7251 - 7256
反应条件
water T=25°C; 168 h; porcine liver esterase, ammonium sulfate, phosphate buffer 7.0 (maintained with aq. NaOH), or with hexane or toluene, other enzymes (lipase from Pseudomonas cepacia and others), other reaction times, relative rates, enantioselectivity; Product distributionEquilibrium constantMechanism;
参考文献
Journal of Organic Chemistry, , vol. 56, # 26 p. 7251 - 7256
参考文献
Acta Chemica Scandinavica, , vol. 50, # 10 p. 918 - 921
反应条件
bromine; oxygen; di-methyltin dichloride; potassium carbonate in water T=0°C; 2 h; DarknessGreen chemistry;
参考文献
William, Julius M.; Kuriyama, Masami; Onomura, Osamu
RSC Advances, 2013 , vol. 3, # 42 p. 19247 - 19250
反应条件
iridium (III) chloride trihydrate; oxygen; sodium carbonate; triphenylphosphine in 1,3,5-trimethyl-benzene T=169°C; 15 h;
参考文献
Aramoto, Hiroomi; Obora, Yasushi; Ishii, Yasutaka
Journal of Organic Chemistry, 2009 , vol. 74, # 2 p. 628 - 633
反应条件
1: [bis(acetoxy)iodo]benzene; AZADO / dichloromethane; water / 1 h / 0 - 20 °C / |Inert atmosphere 2: diethyl ether / 1 h / 0 - 20 °C / |Inert atmosphere View Scheme
参考文献
Shibuya, Masatoshi; Shibuta, Takuro; Fukuda, Hayato; Iwabuchi, Yoshiharu
Organic Letters, 2012 , vol. 14, # 19 p. 5010 - 5013
反应条件
tert.-butylhydroperoxide in decane; acetonitrile T=65°C; 2.5 h;
参考文献
Verma, Sanny; Nandi, Mahasweta; Modak, Arindam; Jain, Suman L.; Bhaumik, Asim
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 11-12 p. 1897 - 1902
反应条件
periodate(1-) in water T=25°C; ΔHR and Eact; Rate constantThermodynamic data;
参考文献
Crescenzi, Vittorio; Gamini, Amelia; Cesaro, Attilio; Delben, Franco; Paoletti, Sergio
Gazzetta Chimica Italiana, 1983 , vol. 113, # 7/8 p. 387 - 392
反应条件
pyridine; 4-(N,N-dimethlyamino)pyridine
参考文献
Inoue, Aya; Misaki, Tomonori; Fujita, Morifumi; Okuyama, Tadashi; Sugimura, Takashi
Tetrahedron Asymmetry, 2013 , vol. 24, # 13-14 p. 833 - 837
反应条件
tert.-butylhydroperoxide; MoVIO2(acetylacetone)2 in chlorobenzene T=60°C; 24 h;
参考文献
Chemistry Letters, , p. 1295 - 1296
