三甲基-三甲基锡烷基硫基锡烷合成路线 （共 16 条）
反应条件
sodium in tetrahydrofuran bis(trimethylstannyl)sulphide and Na mixed in THF, refluxed for 24 h, during which the addn. of Na was repeated 3 times at 1 h intervale. filtered through dry Na2SO4.; evapn., fractional distn., identified by GLC;
参考文献
Capozzi, Giuseppe; Menichetti, Stefano; Ricci, Alfredo; Taddei, Maurizio
Journal of Organometallic Chemistry, 1988 , vol. 344, p. 285 - 288
反应条件
in [3.3.1]nonane Sn sulfide and freshly pptd. Cu heating in nonane in a sealed tube for 40 h at 160°C, liquid fraction decanting off, solid washing with nonane, solvent removing from combined solns.; Me2SnO isolated as Me2SnCl2;
参考文献
Razuvaev, G.A.; Shcherbakov, V.I.; Grigor'Eva, I.K.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 245 - 252
反应条件
methyl iodide in pentane Sn sulfide and MeI refluxing in pentane for 25 h, sulfonium salt filtering off; Sn containing products analyzed by GLC;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 245 - 252
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide in hexane byproducts: diethyl sulfide; a mixt. of Sn sulfide, EtI and HMPT heating under reflux for 8 h, sulfonium salt filtering off, solvent removing under 40 mm Hg at room temp.; purified by distillation in vacuo;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 245 - 252
参考文献
Gmelin Handbook: B: B-Verb.9, 6.3.2, page 303 - 314
参考文献
Vahrenkamp,H.
Journal of Organometallic Chemistry, 1971 , vol. 28, p. 167 - 179
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Gmelin Handbook: B: B-Verb.3, 2.8, page 36 - 38
反应条件
triphenylphosphine in ethanol; acetone byproducts: Ni, triphenylphosphonium sulfide; dropwise addn. of an ethanolic soln. of NiCl2*6H2O to a stirred soln. of ((CH3)3Sn)2S and triphenylphosphine in acetone; refluxing;; filtration;;
参考文献
Doklady Chemistry (English Translation), , vol. 286 - 291, p. 305 - 308
Doklady Akademii Nauk SSSR, , vol. 289, p. 644 - 646
反应条件
in ethanol byproducts: Ni, triphenylphosphonium sulfide, triphenylphosphine; a mixt. of ((CH3)3Sn)2S and ((C6H5)3P)2NiCl2 in ethanol was heated at 95-100°C for 10 h;; distn.;;
参考文献
Doklady Chemistry (English Translation), , vol. 286 - 291, p. 305 - 308
Doklady Akademii Nauk SSSR, , vol. 289, p. 644 - 646
反应条件
in water; acetone dropwise addn. of an aq. soln. of NiCl2*6H2O to a stirred soln. of ((CH3)3Sn)2S in acetone at room temp.; refluxing for 5 h;; filtration;;
参考文献
Doklady Chemistry (English Translation), , vol. 286 - 291, p. 305 - 308
Doklady Akademii Nauk SSSR, , vol. 289, p. 644 - 646
反应条件
in neat (no solvent) Irradiation (UV/VIS); Sn-compd. placed in sealed flask, exposed to daylight radiation for 48 h; solid dissolved in cyclohexane, recrystd., washed; identified by m.p., elem. anal., IR and mass spectra;
参考文献
Craig, Peter J.; Rapsomanikis, Spyridon
Journal of the Chemical Society, Chemical Communications, 1982 , p. 114
