in benzene byproducts: cis-4-t-butylcyclohexanol, trans-4-t-butylcyclohexanol; ketone adding to a soln. of Al deriv. in molar ratio 1:1, stirring for 24 h; organic products analyzed by GLC after hydrolysis;

in toluene; Petroleum ether Kinetics; byproducts: C2H6; (Ar); using Schlenk techniques; addn. of soln. of (C2H5)3Al (12 equiv.) in petroleum ether to stirred suspn. of NdCl3*6H2O (1 equiv.) in toluenefor 20 min at 40, 50, 70 and 90°C; stirring for 240 min; pptn., filtration, washing of solid twice with toluene and drying under vac., removal of solvent from filtrate in vac., elem. anal.;

in Petroleum ether Kinetics; byproducts: C2H6; (Ar); using Schlenk techniques; addn. of TBP (12 equiv.) to soln. of NdCl3*6H2O (1 equiv.); stirring at 20°C for 10 min, heating at 40°C for 20 min, addn. of soln. of (C2H5)3Al (12 equiv.) in petroleum ether; stirring for 45 s; not isolated, detected with use of luminescence spectroscopy, IR and NMR;

in benzene byproducts: NaBr, pent-1-ene; (Ar); an excess of CH2CHCH2Br added to soln. of Na2((Et3Al)2O) in etherat 20°C with stirring (white ppt. formed); then mixt. mixed for 2 h; filtered from ppt. (NaBr); distillate collected at -70°C; GL-chromy.; elem. anal.;

in toluene Kinetics; byproducts: C2H6; 20 °C, 3-8 min, Al:metal=2-10, under Ar;

water Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;

water multistep reaction; Mechanism;

water Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;

water Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;

water Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;