in diethyl ether byproducts: propane, MgCl2; dry atmosphere; addn. of one equiv. of ethereal soln. of C3H7MgCl to Bu3SnH (0.125 mol); exothermic reaction; white soln. refluxed (2 h); addn. of immonium salt (0.1 mol); stirring for 2 h at room temp.; hydrolysis at 0 ° C;; extn. with ether, evapn., distn.,;
参考文献
Elissondo, Bernard; Verlhac, Jean-Baptiste; Quintard, Jean-Paul; Pereyre, Michel
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 267 - 276
in diethyl ether byproducts: propane, MgClI; dry atmosphere; addn. of one equiv. of ethereal soln. of C3H7MgCl to Bu3SnH (0.125 mol); exothermic reaction; white soln. refluxed (2 h); addn. of immonium salt (0.1 mol); stirring for 2 h at room temp.; hydrolysis at 0 ° C;; extn. with ether, evapn., distn.,;
参考文献
Elissondo, Bernard; Verlhac, Jean-Baptiste; Quintard, Jean-Paul; Pereyre, Michel
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 267 - 276
oxygen in tetrahydrofuran; diethyl ether T=-78°C; 2 h;
参考文献
Nguyen, Bao; Chernous, Katya; Endlar, Daniel; Odell, Barbara; Piacenti, Michela; Brown, John M.; Dorofeev, Alexander S.; Burasov, Alexander V.
Angewandte Chemie - International Edition, 2007 , vol. 46, # 40 p. 7655 - 7658
