1: isopropylmagnesium chloride With indium(III) chloride in tetrahydrofuran; hexane T=-78 - 20°C; 2: carbon monoxide; 2-naphthyl trifluoromethanesulfonate With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; hexane T=60°C; 2 h;
参考文献
Lee, Sung Wook; Lee, Kooyeon; Seomoon, Dong; Kim, Sundae; Kim, Hyunseok; Kim, Hyun; Shim, Eunkyong; Lee, Miae; Lee, Seokju; Kim, Misook; Lee, Phil Ho
Journal of Organic Chemistry, 2004 , vol. 69, # 14 p. 4852 - 4855
1: cyclohexenon With C18H16N2; copper dichloride in tetrahydrofuran T=20°C; 1 h; 2: isopropylmagnesium chloride in tetrahydrofuran T=-90°C; 0.333333 h; 3: With ammonium chloride in tetrahydrofuran optical yield given as percent eeenantioselective reaction;
参考文献
Qi, Gao; Judeh, Zaher M.A.
Synthetic Communications, 2012 , vol. 42, # 11 p. 1585 - 1592
in diethyl ether byproducts: propane, MgCl2; dry atmosphere; addn. of one equiv. of ethereal soln. of C3H7MgCl to Bu3SnH (0.125 mol); exothermic reaction; white soln. refluxed (2 h); addn. of immonium salt (0.1 mol); stirring for 2 h at room temp.; hydrolysis at 0 ° C;; extn. with ether, evapn., distn.,;
参考文献
Elissondo, Bernard; Verlhac, Jean-Baptiste; Quintard, Jean-Paul; Pereyre, Michel
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 267 - 276
