aluminum tribromide other Radiation; a mixt. of GeBr4 and tetrabutylgermane in presence of AlBr3 as catalystin a Pyrex tube is irradiated with a light stream of argon for 5 min atatmospheric pressure (microwave irradiation: 300 W) (Ar); identification by (1)H-NMR, gas chromy.;
参考文献
Laurent, Regis; Laporterie, Andre; Dubac, Jacques; Berlan, Jacques
Organometallics, 1994 , vol. 13, p. 2493 - 2495
in cyclohexane byproducts: n-C4H10, n-C8H18; Irradiation (UV/VIS); photolysis (185 nm); 16percent conversion; react. mechanism discussed; 32percent Bu3GeH, 7percent (Bu3Ge)2, and traces of n-C4H10 and n-C8H8 obtained;
参考文献
Nakadaira, Yasuhiro; Zhou, Da-Yang; Kako, Masahiro; Mochida, Kunio
Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan), 1994 , p. 253 - 257
in cyclohexane Irradiation (UV/VIS); photolysis (185 nm); react. mechanism discussed;
参考文献
Nakadaira, Yasuhiro; Zhou, Da-Yang; Kako, Masahiro; Mochida, Kunio
Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan), 1994 , p. 253 - 257
aluminum tribromide other Radiation; a mixt. of GeBr4 and tetrabutylgermane in presence of AlBr3 as catalystin a Pyrex tube is irradiated with a light stream of argon for 5 min atatmospheric pressure (microwave irradiation: 300 W) (Ar); identification by (1)H-NMR, gas chromy.;
参考文献
Laurent, Regis; Laporterie, Andre; Dubac, Jacques; Berlan, Jacques
Organometallics, 1994 , vol. 13, p. 2493 - 2495
aluminium trichloride other Radiation; a mixt. of GeCl4 and tetraalkylgermane in presence of AlCl3 as catalystin a Pyrex tube is irradiated with a light stream of argon for 30 min at atmospheric pressure (microwave irradiation: 300 W) (Ar); identification by (1)H-NMR, gas chromy.;
参考文献
Laurent, Regis; Laporterie, Andre; Dubac, Jacques; Berlan, Jacques
Organometallics, 1994 , vol. 13, p. 2493 - 2495
aluminium trichloride other Radiation; a mixt. of GeCl4 and tetraalkylgermane in presence of AlCl3 as catalystin a Pyrex tube is irradiated with a light stream of argon for 3 min atatmospheric pressure (microwave irradiation: 300 W) (Ar); identification by (1)H-NMR, gas chromy.;
参考文献
Laurent, Regis; Laporterie, Andre; Dubac, Jacques; Berlan, Jacques
Organometallics, 1994 , vol. 13, p. 2493 - 2495
germanium dichloride*dioxane in neat (no solvent) mixed, boiled on an oil bath at 320°C for 40 min, temp. of reaction mixture rose during this period from 127°C to 217°C; distilled under vac.;
参考文献
Russian Journal of General Chemistry, , vol. 64, p. 146 - 146
Zhurnal Obshchei Khimii, , vol. 64, p. 160 - 160
germanium dichloride*dioxane in neat (no solvent)
mixed, boiled on an oil bath at 320°C for 40 min, temp. of reaction mixture rose during this period from 127°C to 217°C; distilled under vac.;
参考文献
Pavlov, K. V.; Shvedov, I. P.
Russian Journal of General Chemistry, 1994 , vol. 64, p. 146 - 146
Zhurnal Obshchei Khimii, 1994 , vol. 64, p. 160 - 160
