1,1,1-三氯甲基乙烷合成路线 （共 11 条）
反应条件
thionyl chloride; triphenyl-phosphine oxide T=20 - 135°C; 1.83333 h; Product distribution / selectivity;
参考文献
BASF SE
Patent: US2008/228016 A1, 2008 ;
Location in patent: Page/Page column 5 ;
反应条件
nitrogen Irradiation.UV-Licht;
参考文献
Urry; Eiszner
Journal of the American Chemical Society, 1952 , vol. 74, p. 5822,5825
反应条件
pyridine; thionyl chloride in chloroform 1.) RT, 3 d, 2.) 110 deg C, 10 h;
参考文献
Dale, Johannes; Fredriksen, Siw B.
Acta Chemica Scandinavica, 1992 , vol. 46, # 3 p. 278 - 282
反应条件
1: 63 percent / 1.) sodium / toluene / Heating; 1.) 20 h; 2.) 3 h 2: 95 percent / hydrochloric acid / H2O; tetrahydrofuran / 0.5 h / Heating 3: thionyl chloride / pyridine / 115 °C View Scheme
参考文献
Liu, Shiuh-Tzung; Yieh, Chien-Hung; Lu, Hui-Jane
Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 44, p. 261 - 266
参考文献
Urry; Eiszner
Journal of the American Chemical Society, 1952 , vol. 74, p. 5822,5825
反应条件
sodium hydroxide in ethanol T=0 - 70°C; Further byproducts given;
参考文献
Boardman, Brian; Hanton, Martin J.; Van Rensburg, Hendrik; Tooze, Robert P.
Chemical Communications, 2006 , # 21 p. 2289 - 2291
反应条件
potassium hydroxide; potassium carbonate in dimethyl sulfoxide T=90 - 130°C;
参考文献
Muth, A.; Walter, O.; Huttner, G.; Asam, A.; Zsolnai, L.; Emmerich, Ch.
Journal of Organometallic Chemistry, 1994 , vol. 468, # 1-2 p. 149 - 164
反应条件
1: chloro-diphenylphosphine With sodium in anhydrous butyl ether T=105°C; 2 h; 2: 2,2-bis(chloromethyl)-1-chloropropane in anhydrous butyl ether T=105°C; 2 h;
参考文献
BASF Aktiengesellschaft
Patent: WO2006/84878 A1, 2006 ;
Location in patent: Page/Page column 20 ;
反应条件
potassium hydroxide; potassium carbonate in dimethyl sulfoxide 1.) 50 deg C, 2 h, 2.) 60 deg C, 6 h;
参考文献
Journal of Organometallic Chemistry, , vol. 468, # 1-2 p. 149 - 164
反应条件
(i) Mg, THF, (ii) /BRN= 506893/; Multistep reaction;
参考文献
McCaffery,E.L.; Shalaby,S.W.
Journal of Organometallic Chemistry, 1965 , vol. 3, p. 101 - 106
