in neat (no solvent) React. of equimolar amt. of starting materials (vac. line, room temp., 10 min).; Removal of Me3SnCl by passing the mixt. through a trap cooled to -95°C (toluene). IR identificatio of resulting compounds.;
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2886 - 2888
in dichloromethane Kinetics; (CH3)4Sn is added to a stirred soln. of (MCOT)PtBr2, soln. is stirred for 2 h.; Solvent is evapd., residue is washed with hexane to remove (CH3)3SnBr, elem. anal., isolated yield of dimeric compound 26percent (ratio trans:cis=3.3:1).;
Bumagin, N. A.; Bumagina, I. G.; Kashin, A. N.; Beletskaya, I. P.
Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 621 - 621
Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 714 - 714
in dichloromethane N2 atmosphere, addn. of soln. of stannyl compound to soln. of borane at -78°C, slow warming to room temp., stirring (25°C, 12 h); removement of solvent (25°C, 12 Torr), removement of Me3SnBr by fractional distillation (30°C, 1E-2 Torr or 53-55°C, 12 Torr); elem. anal.;
参考文献
Diemer, Stefan; Noeth, Heinrich; Storch, Wolfgang
European Journal of Inorganic Chemistry, 1999 , # 9 p. 1765 - 1780
in neat (no solvent) Warming mixt. of equimolar amt. of starting materials (condensed at -196°C) to -80°C (30 min) and then gradually to 10°C.; Removal of Me3SnCl by passing the mixt. through a trap cooled to -95°C (toluene). NMR spectrum indicate presence of major resulting compounds, with small amt. of SiF3SiHBr2 and unreacted SiF3SiFHBr.;
