3,4-二氢二苯并(a,j)吖啶合成路线 （共 9 条）
反应条件
1: 0.5 g / 0.5 h / 260 - 280 °C 2: 83 percent / 10percent Pd/C / various solvent(s) / 8 h / 190 °C 3: 1.) Na, NH3 liq., 2.) AcOH / 1.) THF, 18 h, 2.) 100 deg C to 125 deg C, 18 h 4: 1.) t-BuONa, 2.) DDQ / 1.) t-BuOH, reflux, 15 h, 2.) dioxane, reflux, 15 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 6 p. 1064 - 1072
反应条件
1: 0.5 g / 0.5 h / 260 - 280 °C 2: 83 percent / 10percent Pd/C / various solvent(s) / 8 h / 190 °C 3: 1.) Na, NH3 liq., 2.) AcOH / 1.) THF, 18 h, 2.) 100 deg C to 125 deg C, 18 h 4: 1.) t-BuONa, 2.) DDQ / 1.) t-BuOH, reflux, 15 h, 2.) dioxane, reflux, 15 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 6 p. 1064 - 1072
反应条件
1: 83 percent / 10percent Pd/C / various solvent(s) / 8 h / 190 °C 2: 1.) Na, NH3 liq., 2.) AcOH / 1.) THF, 18 h, 2.) 100 deg C to 125 deg C, 18 h 3: 1.) t-BuONa, 2.) DDQ / 1.) t-BuOH, reflux, 15 h, 2.) dioxane, reflux, 15 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 6 p. 1064 - 1072
反应条件
1: 1.) Na, NH3 liq., 2.) AcOH / 1.) THF, 18 h, 2.) 100 deg C to 125 deg C, 18 h 2: 1.) t-BuONa, 2.) DDQ / 1.) t-BuOH, reflux, 15 h, 2.) dioxane, reflux, 15 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 6 p. 1064 - 1072
反应条件
1: 1.) t-BuONa, 2.) DDQ / 1.) t-BuOH, reflux, 15 h, 2.) dioxane, reflux, 15 h 2: 1.) Na, liq. NH3, EtOH, 2.) AcOH / 1.) THF, 18 h, 2.) 100 deg C, overnight 3: 1.) t-BuONa, 2.) DDQ / 1.) t-BuOH, reflux, 18 h, 2.) dioxane, reflux, 3 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 6 p. 1064 - 1072
反应条件
1: 1.) t-BuONa, 2.) DDQ / 1.) t-BuOH, reflux, 18 h, 2.) dioxane, reflux, 3 h 2: 1.) Na, liq. NH3, EtOH, 2.) AcOH / 1.) THF, 18 h, 2.) 100 deg C, overnight 3: 1.) t-BuONa, 2.) DDQ / 1.) t-BuOH, reflux, 15 h, 2.) dioxane, reflux, 15 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 6 p. 1064 - 1072
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium t-butanolate 1.) t-BuOH, reflux, 15 h, 2.) dioxane, reflux, 15 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 52, # 6 p. 1064 - 1072
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium t-butanolate 1.) reflux, 2.) t-BuOH, reflux; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 52, # 6 p. 1064 - 1072
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium t-butanolate 1.) t-BuOH, reflux, 18 h, 2.) dioxane, reflux, 3 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 52, # 6 p. 1064 - 1072
