1,2:5,6-O-双异丙叉-Alpha-D-己呋喃核糖-3-酮水合物合成路线 （共 8 条）
反应条件
sodium tetrahydroborate
参考文献
Zsoldos-Mady, Virag; Zbiral, Erich
Monatshefte fuer Chemie, 1986 , vol. 117, p. 1325 - 1338
反应条件
3 A molecular sieve; pyridinium chlorochromate in dichloromethane
16 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Lankin; Nugent; Rao
Carbohydrate Research, 1993 , vol. 244, # 1 p. 49 - 68
反应条件
1: O,O-diethyl 1,1-difluoro-1-bromomethane phosphonothioate With tert.-butyl lithium in tetrahydrofuran; pentane
T=-78°C; 0.166667 h;
2: 1,2:5,6-di-O-isopropylidene-α-D-ribo-1,5-hexofuranos-3-ulose in tetrahydrofuran; pentane
T=-78°C; 0.5 h;
参考文献
Lopin, Chrystel; Gautier, Arnaud; Gouhier, Geraldine; Piettre, Serge R.
Journal of the American Chemical Society, 2002 , vol. 124, # 49 p. 14668 - 14675
反应条件
ruthenium(IV) oxide; sodium periodate; N-benzyl-N,N,N-triethylammonium chloride; water; potassium carbonate in chloroform
22 h;
参考文献
Morris, Philip E.; Kiely, Donald E.
Journal of Organic Chemistry, 1987 , vol. 52, # 6 p. 1149 - 1152
反应条件
1: O,O-diethyl 1,1-difluoro-1-bromomethane phosphonothioate With tert.-butyl lithium
T=-78°C;
2: 1,2:5,6-di-O-isopropylidene-α-D-ribo-1,5-hexofuranos-3-ulose T=-78 - 0°C;
参考文献
Lopin, Chrystel; Gautier, Arnaud; Gouhier, Geraldine; Piettre, Serge R.
Journal of the American Chemical Society, 2002 , vol. 124, # 49 p. 14668 - 14675
反应条件
1: (EtO)2P(O)CF2Br With tert.-butyl lithium
T=-78°C;
2: 1,2:5,6-di-O-isopropylidene-α-D-ribo-1,5-hexofuranos-3-ulose T=-78 - 0°C;
参考文献
Lopin, Chrystel; Gautier, Arnaud; Gouhier, Geraldine; Piettre, Serge R.
Journal of the American Chemical Society, 2002 , vol. 124, # 49 p. 14668 - 14675
反应条件
in chloroform; water; isopropyl alcohol
T=0°C; Cycloaddition; 3 h;
参考文献
Hall, Adrian; Bailey, Patrick D.; Rees, David C.; Rosair, Georgina M.; Wightman, Richard H.
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 3 p. 329 - 343
参考文献
Shing, Tony K.M.; Wong, Ching-Hung; Yip, Ting
Tetrahedron Asymmetry, 1996 , vol. 7, # 5 p. 1323 - 1340
