1-(4-氯苯基)-1,2-丙二酮合成路线 (共 14 条)
反应条件
1: 1.) n-BuLi / 1.) toluene, hexane, 15 min, 2.) toluene, hexane, 3 h 2: 39 percent / KMnO4, aq. MgSO4 / toluene / 40 h / 50 - 60 °C View Scheme
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 101, # 1-4 p. 281 - 286
反应条件
1: diethyl ether / 0 °C 2: SeO2 / ethanol / 48 h / Heating View Scheme
参考文献
Bulletin de la Societe Chimique de France, , p. 1921 - 1925
反应条件
1.1: N-chloro-succinimide / N,N-dimethyl-formamide / 3 h / 0 °C / |Inert atmosphere 1.2: 4 h / 20 °C / |Inert atmosphere 2.1: hydrogen / methanol / 5 h / 3620.13 Torr / |Inert atmosphere 3.1: pyridinium chlorochromate / dichloromethane / 2 h / 0 - 20 °C / |Inert atmosphere View Scheme
参考文献
Tetrahedron Letters, , vol. 53, # 39 p. 5327 - 5330
反应条件
steam; sulfuric acid
参考文献
Justus Liebigs Annalen der Chemie, , vol. 528, p. 297