in neat (no solvent)
SO3 is distilled (from 65 percent oleum) into cooled (ice/water) vessel containing SCl2; evolution of SO2;; multiple fractionation (at last in presence of sulfur);;
参考文献
Michaelis, A.
Liebigs Annalen der Chemie, 1893 , vol. 274, p. 173 - 186
Show Details
Gmelin Handbook: S: MVol.B3, 122, page 1791 - 1793
Show Details
Feher, F.
Brauer, G., Handbuch der praeparativen anorganischen Chemie, Stuttgart 1954, S. 294
in dichloromethane
byproducts: AgCl; a soln. of SCl2 cooled to 0°C, Ag salt added, stirred; filtered, evapd. (vac. below 0°C);
参考文献
Burchell, Colin J.; Kilian, Petr; Slawin, Alexandra M. Z.; Woollins, J. Derek; Tersago, Karla; Van Alsenoy, Christian; Blockhuys, Frank
Inorganic Chemistry, 2006 , vol. 45, # 2 p. 710 - 716
in dichloromethane
byproducts: AgCl; a soln. of SCl2 cooled to 0°C, Ag salt added, stirred for ca. 1 h; filtered, evapd. (vac. below 0°C);
参考文献
Burchell, Colin J.; Kilian, Petr; Slawin, Alexandra M. Z.; Woollins, J. Derek; Tersago, Karla; Van Alsenoy, Christian; Blockhuys, Frank
Inorganic Chemistry, 2006 , vol. 45, # 2 p. 710 - 716
