1,2,3,4,5,6,7,8-八硫杂环辛烷合成路线 （共 272 条）
反应条件
hydrogen in gas byproducts: H2O; SO2:H2 gas mixt. at rates of 20:40 cm**3min**-1 under atm. pressure; at above 508 K; Ru/TiO2 obtained from RuCl3; detd. by gas chromy.;
参考文献
Journal of Catalysis, , vol. 206, # 1 p. 159 - 164
反应条件
(.eta.5-C5Me5)2Mo2(mu.-S)2(.mu.-SH)2 in chloroform Kinetics; SO2 (3-8 mmol) and H2 (12-27 mmol, 2.8 atm) stirred in closed flask using 0.04-0.1 mmol of (C5Me5)2Mo2S2(SH)2 (0.0056 M) in CHCl3 at 75°C for 144 h (up to 50-80percent consumption of initial SO2);
参考文献
Journal of the American Chemical Society, , vol. 107, p. 6138 - 6140
反应条件
air; iron(III) sulfate pentahydrate in water H2S and air were bubbled into soln. Fe2(SO4)3*5H2O in N-methylpyrrolidinone-H2O (95:5) at room temp. for 14 h;
参考文献
Dalton Transactions, , vol. 6, # 9 p. 1147 - 1156
反应条件
air; iron(III) chloride in water H2S and air were bubbled into soln. FeCl3 in N-methylpyrrolidinone-H2O (95:5) at room temp. for 300 h;
参考文献
Dalton Transactions, , vol. 6, # 9 p. 1147 - 1156
反应条件
air; iron(III) sulfate pentahydrate in water H2S and air were bubbled into soln. Fe2(SO4)3*5H2O in N-methylpyrrolidinone-H2O (95:5) at room temp. for 80.5 h;
参考文献
Dalton Transactions, , vol. 6, # 9 p. 1147 - 1156
反应条件
PPA; potassium iodide in sulfolane byproducts: I2; polyphosphoric acid, KI added into sulfolane, added H2SO4 and (n-Bu4N)I, stirred under N2 for 8 h at 75°C; excess of polyphosphoric acid hydrolyzed with stirring for 0.5 h at 75°C, mixt. poured into C6H6, washed with H2O, dried, filtered, filtrate evapd., chromd. (SiO2, C6H6), recrystd. from C6H6/hexane;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 56, # 12 p. 3818 - 3823
反应条件
m-phenylenediacetonitrile; Cu(NO3)2*3H2O in methanol High Pressure; heating mixt. in sealed reactor at 180°C;
参考文献
Angewandte Chemie - International Edition, , vol. 44, # 27 p. 4175 - 4178
反应条件
[Ru2(N,N-bis([2,2'-bipyridin-6-yl]methyl)butan-1-amine)(p-cumene)2(chloride)2](2+) in tetrahydrofuran; water byproducts: H2; Irradiation (UV/VIS); under Ar irradiation of soln. of CS2, Ru complex in THF/H2O (1:1), 70°C, 20 h; addn. of H2O, toluene;
参考文献
Inorganic Chemistry, , vol. 50, # 22 p. 11273 - 11275
反应条件
NaF in acetonitrile byproducts: NaCl; exclusion of moisture; addn. of org.compd. suspn. of Mo-compd. and NaF in MeCN, refluxing (4 h); filtn., partial evapn., cooling (5°C), filtn., washing (MeCN), drying (N2 stream); elem. anal.;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 572, p. 26 - 32
反应条件
in gas Irradiation (UV/VIS); irradiation in a thermal diffusion cloud chamber with a pulsed nitrogenlaser with pressure below 10 mm Hg;; detn. by mass spectroscopy;;
参考文献
Journal of Chemical Physics, , vol. 83, # 7 p. 3668 - 3680
