1-(4-乙烯基-苯基)-乙酮合成路线 （共 83 条）
反应条件
hydrogen; tin(ll) chloride; ((2S,4S)-N-(tert-butoxycarbonyl)-4-(diphenylphosphino)-2-{(diphenylphosphino)methyl}pyrrolidine)PtCl2 in benzene T=60°C; P=137044 Torr; 8 h; Yield given. Yields of byproduct given;
参考文献
Parrinello, Giovanni; Stille, J. K.
Journal of the American Chemical Society, 1987 , vol. 109, # 23 p. 7122 - 7127
反应条件
oxygen; palladium diacetate; toluene-4-sulfonic acid in water T=100°C; P=6080.41 Torr; 24 h; Autoclave;
参考文献
Wang, Azhong; Jiang, Huanfeng
Journal of Organic Chemistry, 2010 , vol. 75, # 7 p. 2321 - 2326
反应条件
diisobutylaluminium hydride; triphenylphosphine; bis(acetylacetonate)nickel(II) in ethylene glycol dimethyl ether; hexane
T=80°C; 24 h;
参考文献
Littke, Adam F.; Schwarz, Lothar; Fu, Gregory C.
Journal of the American Chemical Society, 2002 , vol. 124, # 22 p. 6343 - 6348
反应条件
sodium hydroxide; poly(ethylene glycol) 2000; palladium diacetate in water
T=140°C; Hiyama reaction; 3 h;
参考文献
Gordillo, Alvaro; Ortuno, Manuel A.; Lopez-Mardomingo, Carmen; Lledos, Agusti; Ujaque, Gregori; De Jesus, Ernesto
Journal of the American Chemical Society, 2013 , vol. 135, # 37 p. 13749 - 13763
反应条件
1-methyl-piperazine; tetrabutyl ammonium fluoride; N-dicyclohexylphosphino-N-methylpiperazine; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; toluene
T=110°C; Hiyama cross-coupling; 0.3 h; microwave irradiation;
参考文献
Clarke, Matthew L.
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 2-3 p. 303 - 307
反应条件
sodium hydroxide; palladium diacetate in water
T=120°C; 0.166667 h; microwave irradiation;
参考文献
Alacid, Emilio; Najera, Carmen
Journal of Organic Chemistry, 2008 , vol. 73, # 6 p. 2315 - 2322
反应条件
potassium fluoride; Pd (3 wt)/C in N,N-dimethyl-formamide
T=130°C; Hiyama Coupling; P=1500.15 Torr; 5 h; Inert atmosphere;
参考文献
Grirrane, Abdessamad; Garcia, Hermenegildo; Corma, Avelino
Journal of Catalysis, 2013 , vol. 302, p. 49 - 57
反应条件
2C8H8NO2(1-)*2Cl(1-)*2Pd(2+); tetrabutylammomium bromide; potassium carbonate in water
T=120°C; Suzuki-Miyaura coupling; 2 h; Sealed vessel;
参考文献
Alacid, Emilio; Najera, Carmen
Journal of Organic Chemistry, 2009 , vol. 74, # 6 p. 2321 - 2327
反应条件
palladium 10 on activated carbon; LiF in 1-methyl-pyrrolidin-2-one
T=90°C; Stille coupling; 24 h;
参考文献
Yabe, Yuki; Maegawa, Tomohiro; Monguchi, Yasunari; Sajiki, Hironao
Tetrahedron, 2010 , vol. 66, # 45 p. 8654 - 8660
反应条件
tetrabutyl ammonium fluoride; bis(benzonitrile)palladium(II) dichloride in tetrahydrofuran
T=60°C;
参考文献
Itami; Nokami; Yoshida
Journal of the American Chemical Society, 2001 , vol. 123, # 23 p. 5600 - 5601
