1-(3,4-二甲氧基苯基)-2-(2-甲氧基苯基)-丙烷-1,3-二醇合成路线 （共 41 条）
反应条件
oxygen T=170°C; 3 h; Further byproducts given;
参考文献
Journal of Organic Chemistry, , vol. 53, # 8 p. 1673 - 1679
反应条件
oxygen T=170°C; 3 h; Further byproducts given;
参考文献
Journal of Organic Chemistry, , vol. 53, # 8 p. 1673 - 1679
反应条件
oxygen; anhydrous cobalt diacetate; acetic acid T=170°C; P=25857.4 Torr; 3 h; var. reaction partner systems; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 53, # 8 p. 1673 - 1679
反应条件
sodium hydroxide in water T=150 - 160°C; electrochemical oxidation; other conditions: other solvents, other reagents, reaction in the presence of tris(4-bromophenyl)amine as mediator, other temperature, different electrodes; <other lignin model dimers as starting material>; Product distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 56, # 26 p. 7305 - 7313
反应条件
potassium peroxomonosulphate; manganese porphyrin in water; acetonitrile 0.25 h; Ambient temperatureoxidation catalyzed by various supported porphyrins on regular ion-exchange resins or on a poly(vinylpyridinium)polymer; Product distribution;
参考文献
Bulletin de la Societe Chimique de France, , vol. 131, # 1 p. 78 - 88
反应条件
1: silica gel; C26H51N2O2(1+)*BF4(1-) / dichloromethane / 15 h / 20 °C 2: formic acid; [Ir(phenylpyridine(-1H))2(4,4′-di-tert-butyl-2,2′-bipyridine)](PF6); N-ethyl-N,N-diisopropylamine / acetonitrile / 48 h / 20 °C / |Irradiation View Scheme
参考文献
Journal of the American Chemical Society, , vol. 136, # 4 p. 1218 - 1221
反应条件
sodium hydroxide in water T=150 - 160°C; electrochemical oxidation; other conditions: other solvents, other reagents, reaction in the presence of tris(4-bromophenyl)amine as mediator, other temperature, different electrodes; <other lignin model dimers as starting material>; Product distributionMechanism;
参考文献
Pardini, Vera L.; Smith, Carmen Z.; Utley, James H. P.; Vargas, Reinaldo R.; Viertler, Hans
Journal of Organic Chemistry, 1991 , vol. 56, # 26 p. 7305 - 7313
反应条件
sodium hydroxide in water T=150 - 160°C; electrochemical oxidation; other conditions: other solvents, other reagents, reaction in the presence of tris(4-bromophenyl)amine as mediator, other temperature, different electrodes; <other lignin model dimers as starting material>; Product distributionMechanism;
参考文献
Pardini, Vera L.; Smith, Carmen Z.; Utley, James H. P.; Vargas, Reinaldo R.; Viertler, Hans
Journal of Organic Chemistry, 1991 , vol. 56, # 26 p. 7305 - 7313
反应条件
isopropyl alcohol in ethyl acetate
T=100°C; 24 h; Overall yield = > 95 percentSpectr.;
参考文献
KAT2BIZ AB; SAMEC, Joseph; GALKIN, Maxim
Patent: WO2014/38989 A1, 2014 ;
Location in patent: Page/Page column 5 ;
反应条件
1: With 1,10-phenanthroline; potassium carbonate; copper(I) bromide; diethylazodicarboxylate in toluene
T=20°C; 0.25 h;
2: With oxygen in toluene
T=90°C; P=760.051 Torr; 1.5 h; chemoselective reaction;
参考文献
Zhang, Jian; Liu, Yu; Chiba, Shunsuke; Loh, Teck-Peng
Chemical Communications, 2013 , vol. 49, # 97 p. 11439 - 11441
