2-乙酰氨基-1,2,5-三脱氧-1,5-亚氨基-d-葡萄糖醇合成路线 （共 38 条）
反应条件
hydrogen; palladium in acetic acid 24 h;
参考文献
Fleet, George W. J.; Fellows, L. E.; Smith, Paul W.
Tetrahedron, 1987 , vol. 43, # 5 p. 979 - 990
反应条件
hydrogenchloride; hydrogen; palladium hydroxide - carbon in methanol P=760 Torr; 5 h;
参考文献
Furneaux; Gainsford; Lynch; Yorke
Tetrahedron, 1993 , vol. 49, # 42 p. 9605 - 9612
反应条件
acetic acid in water T=60°C; 8 h;
参考文献
Boeshagen; Heiker; Schueller
Carbohydrate research, 1987 , vol. 164, p. 141 - 148
反应条件
palladium on carbon; hydrogen; ammonium formate in methanol; water T=20°C; P=760.051 Torr; 48 h;
参考文献
Stubbs, Keith A.; Bacik, John-Paul; Perley-Robertson, G. Evan; Whitworth, Garrett E.; Gloster, Tracey M.; Vocadlo, David J.; Mark, Brian L.
ChemBioChem, 2013 , vol. 14, # 15 p. 1973 - 1981
反应条件
hydrogen; palladium dihydroxide in ethanol
参考文献
Gradnig, Guenther; Legler, Guenter; Stuetz, Arnold E.
Carbohydrate Research, 1996 , vol. 287, p. 49 - 57
反应条件
1: 89 percent / acetic acid; H2O / 5 h / Ambient temperature 2: 1.) dibutyltin oxide, 2.) Br2, tributyltin methoxide / 1.) 0 deg C, 2.) CH2Cl2 3: aq. H2SO4 / 3.25 h / 60 °C 4: sodium cyanoborohydride / methanol / 336 h / in a refrigerator 5: 49 percent / H2, HCl / Pd(OH)2 on carbon / methanol / 5 h / 760 Torr View Scheme
参考文献
Tetrahedron, , vol. 49, # 42 p. 9605 - 9612
反应条件
1: 1.) dibutyltin oxide, 2.) Br2, tributyltin methoxide / 1.) 0 deg C, 2.) CH2Cl2 2: aq. H2SO4 / 3.25 h / 60 °C 3: sodium cyanoborohydride / methanol / 336 h / in a refrigerator 4: 49 percent / H2, HCl / Pd(OH)2 on carbon / methanol / 5 h / 760 Torr View Scheme
参考文献
Tetrahedron, , vol. 49, # 42 p. 9605 - 9612
反应条件
1: 83 percent / p-toluenesulfonic acid / 3 h / pH 3-4 2: 89 percent / acetic acid; H2O / 5 h / Ambient temperature 3: 1.) dibutyltin oxide, 2.) Br2, tributyltin methoxide / 1.) 0 deg C, 2.) CH2Cl2 4: aq. H2SO4 / 3.25 h / 60 °C 5: sodium cyanoborohydride / methanol / 336 h / in a refrigerator 6: 49 percent / H2, HCl / Pd(OH)2 on carbon / methanol / 5 h / 760 Torr View Scheme
参考文献
Tetrahedron, , vol. 49, # 42 p. 9605 - 9612
反应条件
Dowex (50W-X8, H+) in water Inert atmosphere;
参考文献
Glawar, Andreas F. G.; Best, Daniel; Ayers, Benjamin J.; Miyauchi, Saori; Nakagawa, Shinpei; Aguilar-Moncayo, Matilde; Garcia Fernandez, Jose M.; Ortiz Mellet, Carmen; Crabtree, Elizabeth V.; Butters, Terry D.; Wilson, Francis X.; Kato, Atsushi; Fleet, George W. J.
Chemistry - A European Journal, 2012 , vol. 18, # 30 p. 9341 - 9359
反应条件
ammonium acetate; sodium cyanoborohydride in methanol T=0 - 4°C; 1.) 0-4 deg C, 7 d, 2.) RT, 1 d; Yield given;
参考文献
Tetrahedron, , vol. 49, # 42 p. 9605 - 9612
