CM-phos; palladium diacetate; potassium carbonate in water; tert-butyl alcohol T=80°C; 18 h; Inert atmosphere;

1: With [(k2-P,N-di(1-adamantyl)-2-morpholinophenylphosphine)Pd(Ph)Cl]; sodium t-butanolate in 1,4-dioxane Inert atmosphereGlovebox; 2: With ammonia in 1,4-dioxane T=24°C; Inert atmosphereGlovebox;

1,1'-bis-(diphenylphosphino)ferrocene; (9-phenanthrenyl)Ni(II)(PPh3)2Cl; potassium carbonate in toluene T=110°C; Suzuki Coupling; 18 h; Inert atmosphere;