1: With ozone in dichloromethane T=-78°C; 2: With (Z,Z,Z)-4,4'-bis[4-(diphenylphosphino)styryl]stilbene in dichloromethane T=-78 - 23°C; 0.5 h; 3: With 2,4,5,7-tetraiodofluorescein in tetrahydrofuran 1 h; Irradiation;
参考文献
Bosanac, Todd; Wilcox, Craig S.
Organic Letters, 2004 , vol. 6, # 14 p. 2321 - 2324
1H-imidazole; C84H72ClFeN4O12S4(4-)*4Na(1+); dihydrogen peroxide in methanol; water pH=4; 1 h; Inert atmosphereaq. buffer; optical yield given as percent eeenantioselective reaction;