2-苄基-2-羰基甲氧基环戊酮合成路线 （共 8 条）
反应条件
hydrogenchloride; acetic acid Heating;
参考文献
Wang, Shaozhao; Chen, Gang; Kayser, Margaret M.; Iwaki, Hiroaki; Lau, Peter C.K.; Hasegawa, Yoshie
Canadian Journal of Chemistry, 2002 , vol. 80, # 6 p. 613 - 621
反应条件
potassium carbonate in acetone
2 h; Heating;
参考文献
Teixeira, Lis H. P.; Barreiro, Eliezer J.; Fraga, Carlos A. M.
Synthetic Communications, 1997 , vol. 27, # 18 p. 3241 - 3257
反应条件
chloro-trimethyl-silane; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in tetrahydrofuran
T=20°C; 18 h;
参考文献
Le Notre, Jerome; Van Mele, David; Frost, Christopher G.
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 3 p. 432 - 440
反应条件
chloro-trimethyl-silane; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in tetrahydrofuran
T=20°C; 18 h;
参考文献
Le Notre, Jerome; Van Mele, David; Frost, Christopher G.
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 3 p. 432 - 440
反应条件
chloro-trimethyl-silane; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in tetrahydrofuran
T=20°C; 18 h;
参考文献
Le Notre, Jerome; Van Mele, David; Frost, Christopher G.
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 3 p. 432 - 440
反应条件
chloro-trimethyl-silane; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in tetrahydrofuran
T=20°C; 18 h;
参考文献
Le Notre, Jerome; Van Mele, David; Frost, Christopher G.
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 3 p. 432 - 440
反应条件
potassium hydroxide; [Rh(COD)2][SbF6] in tetrahydrofuran
T=80°C; 20 h;
参考文献
Le Notre, Jerome; Van Mele, David; Frost, Christopher G.
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 3 p. 432 - 440
反应条件
1.1: NaH / dimethylformamide / 0.5 h / 20 °C
1.2: dimethylformamide / 16 h / 100 °C
2.1: 710 mg / K2CO3 / dimethylformamide / 6 h / 100 °C
3.1: KOH / [Rh(COD)2][SbF6] / tetrahydrofuran / 20 h / 80 °C
View Scheme
参考文献
Le Notre, Jerome; Van Mele, David; Frost, Christopher G.
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 3 p. 432 - 440
