(6R)-8-溴-2,6-二甲基-2-辛烯合成路线 （共 6 条）
反应条件
tetra-n-butylammonium tetrafluoroborate; (1,4,8,11-tetraazacyclotetradecane)nickel(II) perchlorate in N,N-dimethyl-formamide T=20°C; Cyclization; Electrochemical reaction;
参考文献
Tetrahedron Letters, , vol. 40, # 49 p. 8693 - 8696
反应条件
tetra-n-butylammonium tetrafluoroborate; (1,4,8,11-tetraazacyclotetradecane)nickel(II) perchlorate in N,N-dimethyl-formamide T=20°C; Cyclization; Electrochemical reaction;
参考文献
Tetrahedron Letters, , vol. 40, # 49 p. 8693 - 8696
反应条件
potassium tert-butylate in tetrahydrofuran 48 h;
参考文献
Nugent, William A.; Feldman, Jerald; Calabrese, Joseph C.
Journal of the American Chemical Society, 1995 , vol. 117, # 35 p. 8992 - 8998
反应条件
1: various solvent(s) / 0.75 h / 60 °C 2: NaOH / ethanol / 4 h / 20 - 75 °C / 0.5 Torr View Scheme
参考文献
Zhao, Cheng-Hua; Millar, Jocelyn G.; Pan, Kun-Hui; Cai-Sheng
Journal of Chemical Ecology, 1998 , vol. 24, # 8 p. 1347 - 1353
反应条件
1: With 3-chloro-benzenecarboperoxoic acid in chloroform Oxidation; 2: With sodium periodate in tetrahydrofuran; water oxidative cleavage;
参考文献
Markowski, Thomas; Drescher, Simon; Meister, Annette; Hause, Gerd; Blume, Alfred; Dobner, Bodo
European Journal of Organic Chemistry, 2011 , # 29 p. 5894 - 5904
反应条件
Stage #1: 1-bromo-hexane With magnesium in tetrahydrofuran 1 h; Heating; Stage #2: (S)-(+)-citronellyl bromide With lithium tetrachlorocuprate in tetrahydrofuran T=-78 - 20°C; Grignard reaction;
参考文献
Roberts, Ieuan O.; Baird, Mark S. Chemistry and Physics of Lipids, 2006 , vol. 142, # 1-2 p. 111 - 117
