2-甲基-4-苯基-2-丁醇合成路线 （共 84 条）
反应条件
1: With [2,2']bipyridinyl; trimethylsilyl trifluoromethanesulfonate in dichloromethane T=0°C; 0.5 h; Inert atmosphere; 2: With water in diethyl ether; dichloromethane T=20°C; 1 h; Inert atmosphere; chemoselective reaction;
参考文献
Fujioka, Hiromichi; Minamitsuji, Yutaka; Kubo, Ozora; Senami, Kento; Maegawa, Tomohiro
Tetrahedron, 2011 , vol. 67, # 16 p. 2949 - 2960
反应条件
1: With [2,2']bipyridinyl; trimethylsilyl trifluoromethanesulfonate in dichloromethane T=0°C; 0.5 h; Inert atmosphere; 2: With water in dichloromethane T=20°C; 1 h; Inert atmosphere; chemoselective reaction;
参考文献
Fujioka, Hiromichi; Minamitsuji, Yutaka; Kubo, Ozora; Senami, Kento; Maegawa, Tomohiro
Tetrahedron, 2011 , vol. 67, # 16 p. 2949 - 2960
反应条件
1: With [2,2']bipyridinyl; trimethylsilyl trifluoromethanesulfonate in dichloromethane T=0°C; 0.5 h; Inert atmosphere; 2: With water in dichloromethane T=20°C; 1 h; Inert atmosphere; chemoselective reaction;
参考文献
Fujioka, Hiromichi; Minamitsuji, Yutaka; Kubo, Ozora; Senami, Kento; Maegawa, Tomohiro
Tetrahedron, 2011 , vol. 67, # 16 p. 2949 - 2960
反应条件
copper(l) iodide in tetrahydrofuran; toluene T=-10 - 0°C; 3 h;
参考文献
BASF SE; Rüdenauer, Stefan
Patent: US2014/73819 A1, 2014 ;
Location in patent: Paragraph 0027 ;
反应条件
ammonium formate; palladium on activated charcoal in ethanol T=23°C; 5 h;
参考文献
Dragovich, Peter S.; Prins, Thomas, J.; Zhou, Ru
Journal of Organic Chemistry, 1995 , vol. 60, # 15 p. 4922 - 4924
反应条件
phosphoric acid; 5 palladium on charcoal; hydrogen T=80 - 105°C; P=7500.75 - 11251.1 Torr; 36 h; Inert atmosphereAutoclaveLarge scale;
参考文献
FIRMENICH SA; VANHESSCHE, Koenraad P.; LERESCHE, Jean-Paul
Patent: WO2014/1266 A1, 2014 ;
Location in patent: Page/Page column 8 ;
反应条件
in tetrahydrofuran T=0°C; 1 h;
参考文献
Ho, Jinn-Hsuan; Lee, Ya-Wen; Chen, Ying-Zhe; Chen, Pin-Sian; Liu, Wei-Qi; Ding, Yi-Shun
Tetrahedron, 2013 , vol. 69, # 35 p. 7325 - 7332
反应条件
5 palladium on charcoal; hydrogen T=90°C; P=10501.1 Torr; 5 h; AutoclaveInert atmosphere;
参考文献
FIRMENICH SA; VANHESSCHE, Koenraad P.; LERESCHE, Jean-Paul
Patent: WO2014/1266 A1, 2014 ;
Location in patent: Page/Page column 8-9 ;
反应条件
strontium in tetrahydrofuran T=20°C; Barbier reaction; 0.5 h;
参考文献
Miyoshi, Norikazu; Matsuo, Tsuyoshi; Wada, Makoto
European Journal of Organic Chemistry, 2005 , # 20 p. 4253 - 4255
反应条件
oxygen; cobalt(II) 2,4-pentanedionate in isopropyl alcohol T=75°C; 1 h;
参考文献
Chemistry Letters, , p. 449 - 452
