反应条件
in neat (no solvent) Teflon-valve-equipped standard vacuum line or a nitrogen-filled glovebox;excess B5H9;pentaborane, B2Br4 separately condensed in the reactor, after 20 min at room temp., vessel cooled to -10 ° C,; over course of the following 10 h,all volatile material removed,reactor warmed to room temp.,all volatile material at room temp. were removed,BBr2B5H8 extd. with CH2Cl2, yield:80percent on basis of amt. of B2Br4 employed, 86percent on basis of unrecovered B5H9;
参考文献
Saulys, D. A.; Morrison, J. A.
Inorganic Chemistry, 1990 , vol. 29, p. 4174 - 4179
