copper(l) iodide in diethyl ether hydrogermane mixed with 2 equiv. of CuCl2 and CuI in ether under room temp. for 1 h; solvent evapd., distilled under reduced pressure;
in benzene byproducts: t-BuOH; Irradiation (UV/VIS); digermane soln. irradiating in the presence of an excess of t-Bu2O2 for30 min; product content detd. by high-pressure chromy.;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Guyot, D.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206
water in N,N,N',N',N'',N''-hexamethylphosphoric triamide To a soln. of Et3GeLi is added Et2Ge(H)Cl at room temp., mixt. is stirred for 1 h (dry Ar).; detected by GLC;;
参考文献
Journal of Organometallic Chemistry, , vol. 369, p. 29 - 42
in benzene byproducts: HCl; heating in a sealed tube at 80 ° C for 12 h,; concn. (reduced pressure), anal. (IR, H-NMR, MS); 13percent starting germane;
参考文献
Journal of Organometallic Chemistry, , vol. 339, p. 51 - 60
triethylamine in benzene byproducts: (C2H5)3NHCl; Et3N adding in excess to germane soln. in benzene, stirring at ambient temp., Et3NHCl filtering off, ligand adding, heating in a sealed tube for 3 h at 100°C;
参考文献
Riviere, P.; Castel, A.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 123 - 136
in benzene byproducts: HCl; heating in a sealed tube at 80 ° C for 12 h,; concn. (reduced pressure), anal. (IR, H-NMR, MS); 13percent starting germane;
参考文献
Journal of Organometallic Chemistry, , vol. 339, p. 51 - 60
water in N,N,N',N',N'',N''-hexamethylphosphoric triamide To a soln. of Et3GeLi is added Et2Ge(H)Cl at room temp., mixt. is stirred for 1 h (dry Ar).; detected by GLC;;
参考文献
Journal of Organometallic Chemistry, , vol. 369, p. 29 - 42
