(2Z,4Z)-2,4-环辛四烯并二烯-1-酮合成路线 （共 4 条）
反应条件
oxygen; bis(acetylacetonate)oxovanadium in 1,2-dichloro-ethane T=50°C;
参考文献
Kaneda, Kiyotomi; Jitsukawa, Koichiro; Itoh, Takashi; Teranishi, Shiichiro
Journal of Organic Chemistry, 1980 , vol. 45, p. 3004 - 3009
反应条件
1: With selenium(IV) oxide; oxygen Oxidation; Acetylation; 12 h; Heating; 2: With lithium aluminium tetrahydride in tetrahydrofuran; diethyl ether T=36 - 40°C; Reduction; 2 h; 3: With tetrapropylammonium perruthennate; 4 A molecular sieve; 4-methylmorpholine N-oxide T=20°C; Oxidation; 3 h;
参考文献
Koltun; Kass
Synthesis, 2000 , # 10 p. 1366 - 1368
反应条件
1: 53 percent / NBS 2: 96 percent / NaHCO3 / acetone; H2O / Heating 3: 63 percent / CrO3 / acetone / -5 - 0 °C View Scheme
参考文献
Hanold, Norbert; Meier, Herbert
Chemische Berichte, 1985 , vol. 118, # 1 p. 198 - 209
反应条件
1: (i) NaH, DMSO, (ii) /BRN= 6911720/ 2: 650 °C / 10 Torr 3: H2 / Pd-C / hexane View Scheme
参考文献
Paquette,L.A. et al.
Journal of Organic Chemistry, 1973 , vol. 38, p. 3257 - 3268
