4-苯基四氢呋喃-2-酮合成路线 （共 38 条）
反应条件
N-bromosuccinmide; 2,2'-azo-bisisobutyronitrile in tetrachloromethane Heating;
参考文献
Mehta, Goverdhan; Sengupta, Saumitra
Tetrahedron Letters, 1996 , vol. 37, # 47 p. 8625 - 8626
反应条件
1.1: lithium hexamethyldisilazane / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere 1.2: 1.5 h / -78 - 20 °C / Inert atmosphere 1.3: 16 h / 20 °C / Inert atmosphere 2.1: Rh2(Piv)4 / dichloromethane / 1 h / -50 °C / Inert atmosphere View Scheme
参考文献
Deangelis, Andrew; Dmitrenko, Olga; Fox, Joseph M.
Journal of the American Chemical Society, 2012 , vol. 134, # 26 p. 11035 - 11043
反应条件
bis{2-[(4S,5S)-4-tBuMe2SiOCH2-5-iPr-2-oxazolinyl]phenyl}Se2; dihydrogen peroxide; scandium tris(trifluoromethanesulfonate) in tetrahydrofuran; water
T=20°C; Baeyer-Villiger oxidation; pH=7.4; 24 h;
参考文献
Miyake, Yoshihiro; Nishibayashi, Yoshiaki; Uemura, Sakae
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 10 p. 2233 - 2237
反应条件
palladium 10 on activated carbon; hydrogen in methanol
P=1500.15 Torr;
参考文献
Verendel, J. Johan; Li, Jia-Qi; Quan, Xu; Peters, Byron; Zhou, Taigang; Gautun, Odd R.; Govender, Thavendran; Andersson, Pher G.
Chemistry - A European Journal, 2012 , vol. 18, # 21 p. 6507 - 6513
反应条件
water; [Rh(NCMe)2(cod)][BF4] in tetrahydrofuran
T=60°C;
参考文献
Oi, Shuichi; Moro, Mitsutoshi; Ito, Hisanori; Honma, Yoshio; Miyano, Sotaro; Inoue, Yoshio
Tetrahedron, 2002 , vol. 58, # 1 p. 91 - 97
反应条件
dihydrogen peroxide in hexane; dichloromethane; ethyl acetate
参考文献
Kyushu University
Patent: US2003/120091 A1, 2003 ;
反应条件
1: With [Rh(acac)2(CO)2]; hydrogen; triphenylphosphine in benzene
T=75°C; P=20686.5 Torr; 16 h;
2: With sodium acetate; pyridinium chlorochromate in dichloromethane
12 h; Molecular sieve; regioselective reaction;
参考文献
Sun; Frimpong; Tan
Journal of the American Chemical Society, 2010 , vol. 132, # 34 p. 11841 - 11843
反应条件
1: With ammonium acetate in dimethyl sulfoxide
T=20°C; 14 h;
2: With sodium tetrahydroborate in dimethyl sulfoxide
T=40°C; 2 h;
3: With acetic acid in dimethyl sulfoxide
T=40°C; 2 h;
参考文献
Hoefgen, Barbara; Decker, Michael; Mohr, Patrick; Schramm, Astrid M.; Rostom, Sherif A. F.; El-Subbagh, Hussein; Schweikert, Peter M.; Rudolf, Dirk R.; Kassack, Matthias U.; Lehmann, Jochen
Journal of Medicinal Chemistry, 2006 , vol. 49, # 2 p. 760 - 769
反应条件
ReH7(i-Pr3P)2 in benzene
T=65°C; 29 h;
参考文献
Lin, Yingrui; Zhu, Xianchao; Zhou, Yuefen
Journal of Organometallic Chemistry, 1992 , vol. 429, # 2 p. 269 - 274
反应条件
1: zinc/copper couple; trichlorophosphate / diethyl ether / Reflux
2: acetic acid; zinc / 7 h / 20 - 80 °C
3: dihydrogen peroxide; AcrH(+)ClO4(-) / water; acetonitrile / 20 h / 20 °C / UV-irradiation
View Scheme
参考文献
Xu, Hua-Jian; Zhu, Feng-Fei; Shen, Yong-Ya; Wan, Xin; Feng, Yi-Si
Tetrahedron, 2012 , vol. 68, # 22 p. 4145 - 4151
