dichloromethane in dichloromethane byproducts: CH2ClF, CHClF2, CHCl2F; inert atmosphere; excess of CH2Cl2, warming to room temp., 4 h; further byproduct;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 18 p. 1429 - 1430
H2 in neat (no solvent) anhydrous atmosphere; activation of Re by static hydrogenation (573 K), then heating with ReOF5 (stainless-steel autoclave, 473 K, 16 h); cooling to room temp., removal of volatiles (vac.);
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 11 p. 3127 - 3132
HF in hydrogen fluoride byproducts: CO, Xe; HF (liquid); vac. line; addn. of 4-5 molar equiv. of XeF2 to Re-complex; evapn. (vac.); unchanged Re2(CO)10 present in product with molar ratio of educts 1:1 and 1:2;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 2230 - 2235
