in water Application of RuCl3 from aq. soln. to γ-Al2O3, followed by drying in air at 383 K and redn. in a stream of H2 in a flow-through reactor at 723 K for 2 h and then at 773 K for 1 h.;
参考文献
Theoretical and Experimental Chemistry, , vol. 24, p. 68 - 74
Teoreticheskaya i Eksperimental'naya Khimiya, , vol. 24, p. 75 - 81
reduction in presence of triphenylphosphine under N2 atmosphere at room temperature, either in benzene or THF;; recrystn. from benzene, toluene or THF;;
in ethanol (N2); RuCl3 and ligand in EtOH were refluxed for 3 h, on cooling to room temp. pptd. brown solid; pptn. filtered out, washed with EtOH, ether and pentane, drying in vac. yielded main product; chromy. of the vol. reduced washings (alumina, ether) and removal of solvents afforded decamethylruthenocene;
参考文献
Journal of the American Chemical Society, , vol. 110, p. 6130
NaBH4 in ethanol; water soln. of NaBH4 in 50percent aq. EtOH was added dropwise to a soln. of C5Me5H and RuCl3 in 90percent EtOH at 45°C, mixt. was stirred for 5 h at 45°C; filtered, residue was washed with benzene, combined org. exts. were evapd., residue was dissolved in acetone, cooled, ppt. was recrystd. from acetone;
参考文献
Kreindlin, A. Z.; Petrovskii, P. V.; Rybinskaya, M. I.; Yanovskii, A. I.; Struchkov, Yu. T.
Journal of Organometallic Chemistry, 1987 , vol. 319, p. 229 - 238
hydrogenchloride; sodium chlorate in water distg. off RuO4 from an aq. soln. of 6.5-29 mmol/l Ru chloride, 0.1-0.8 mol/l HCl and 6.5-205 mmol/l NaClO3; rate of distn. increased with higher conc. of chlorate, decreased with higher conc. of HCl;;
in ethanol (N2); RuCl3 and ligand in EtOH were refluxed for 3 h, on cooling to room temp. pptd. brown solid; pptn. filtered out, washed with EtOH, ether and pentane, drying in vac. yielded main product; chromy. of the vol. reduced washings (alumina, ether) and removal of solvents afforded decamethylruthenocene;
参考文献
Journal of the American Chemical Society, , vol. 110, p. 6130
