ClO2(1-); sodium bromite in water
Kinetics; byproducts: H2O; ClO2 disproprotionated in H2O soln. in presence of NaBrO2 and ClO2(1-) at 25°C; monotored by stopped-flow spectrophotometry;
参考文献
Wang, Lu; Nicoson, Jeffrey S.; Huff Hartz, Kara E.; Francisco, Joseph S.; Margerum, Dale W.
Inorganic Chemistry, 2002 , vol. 41, # 1 p. 108 - 113
in water
oxidation in neutral soln.; slow oxidation in acidic soln.;;
参考文献
Dodgen, H.; Taube, H.
Journal of the American Chemical Society, 1949 , vol. 71, p. 2501 - 2504
Full Text View citing articles Show Details
Gmelin Handbook: Cl: SVol.B2, 35, page 391 - 393
H2O; OH(1-) in water
Kinetics; addn. of ClO2 to soln. of HOCl (excess) and buffer (phosphate or carbonate) in all-glass stoppered vessel (pH range 6.34-10.49), sealing, holding at 15-70°C typically for 2 h; monitoring by ion chromy. and UV;
参考文献
Csordas; Bubnis; Fabian; Gordon
Inorganic Chemistry, 2001 , vol. 40, # 8 p. 1833 - 1836
water in water
side reaction of reaction of HClO2 and HClO in weakly acidic or neutral soln. at ambient temp.; excess of ClO(1-); influence of higher temp. and concn.;;
参考文献
White, J. F.; Taylor, M. C.; Vincent, G. P.
Industrial and Engineering Chemistry, 1942 , vol. 34, p. 782 - 792
Full Text Show Details
Gmelin Handbook: Cl: SVol.B2, 40, page 402 - 404
