sodium hypochlorite; 4-phenylpyridine-N-oxide; chiral Mn-salen in dichloromethane T=-20°C; varying ligand in chiral catalyst; Product distribution;

Multistep reaction;

1: LiAlH4 2: KHSO4 View Scheme

(8R,9S)-DHQD-H in 1,2-dichloro-benzene T=20°C; base-catalysed substrate-enantioselective 1,3-hydron transfer (kinetic resolution) and kinetic isotope effect investigated by polarimetric and NMR spectrometric methods; Product distributionRate constant;