1,4-二氧杂螺[4.5]癸-6-烯合成路线 （共 25 条）
反应条件
in pentane
10 h; Ambient temperature; Yield given;
参考文献
Mioskowski, Charles; Manna, S.; Falck, J. R.
Tetrahedron Letters, 1984 , vol. 25, # 5 p. 519 - 522
反应条件
1: 80percent m-CPBA / CH2Cl2 / 15 h / 0 - 15 °C
2: 87 percent / LiAlH4 / tetrahydrofuran / 8 h / Heating
View Scheme
参考文献
Vankar, Yashwant D.; Chaudhuri, Narayan C.; Rao, C. Trinadha
Tetrahedron Letters, 1987 , vol. 28, # 5 p. 551 - 554
反应条件
1: 80percent m-CPBA / CH2Cl2 / 15 h / 0 - 15 °C
2: 87 percent / LiAlH4 / tetrahydrofuran / 8 h / Heating
3: 90 percent / pyridine, chromium trioxide, celite / CH2Cl2 / 0.67 h / 20 - 25 °C
View Scheme
参考文献
Vankar, Yashwant D.; Chaudhuri, Narayan C.; Rao, C. Trinadha
Tetrahedron Letters, 1987 , vol. 28, # 5 p. 551 - 554
反应条件
1: 89 percent / N-bromosuccinimide / dimethylsulfoxide; H2O / 10 °C
2: 65 percent / pyridine, chromium trioxide, celite / CH2Cl2 / 20 - 25 °C
3: 81 percent / tributyltinhydride, AIBN / benzene / 4 h / Heating
View Scheme
参考文献
Vankar, Yashwant D.; Chaudhuri, Narayan C.; Rao, C. Trinadha
Tetrahedron Letters, 1987 , vol. 28, # 5 p. 551 - 554
反应条件
anhydrous palladium in acetone
23 h; Ambient temperature;
参考文献
Lipshutz, Bruce H.; Pollart, Daniel; Monforte, Joseph; Kotsuki, Hiyoshizo
Tetrahedron Letters, 1985 , vol. 26, # 6 p. 705 - 708
