hydrogenchloride; water byproducts: H2, NH3; with hot HCl;

T=110°C;

bromine

RhH(CO)(triphenylphosphine)3; (+)-1,2-bis(diphenylphosphino)propane in toluene T=25°C; P=1199.64 Torr; 10 h; Product distribution / selectivity;

RhH(CO)(triphenylphosphine)3 in toluene (N2 or Ar); sealing of bottle with N,N',N''-trimethylborazine (10 mmol) and RhH(CO)(PPh3)3 (2 mol percent) in MePh (3 ml); charging with ethylene (8 kg/cm**2); stirring at 25°C for 16 h; Kugelrohr distn., GC analysis;

1,3-bis-(diphenylphosphino)propane in toluene (N2 or Ar); sealing of bottle with N,N',N''-trimethylborazine (10 mmol),dppp (0.1 molpercent) and RhF(CO)(PPh3)2 (0.1 mol percent) in toluene (0.3 ml); cha rging with ethylene (8 kg/cm**2); stirring at 50°C for 16 h; Kugelrohr distn., GC analysis;

RhCl(PPh3)3 in toluene T=20°C; 16 h; Product distribution; Further Variations:CatalystsReagentsTemperatures;

暂无反应条件数据