in neat (no solvent) Os is heated in a porcelain boat in a glass tube to 650 - 700 °C in a stream of Cl2;; purification by sublimation in vac.;;
参考文献
Ruff, O.; Bornemann, F.
Z. Anorg. Chem., 1910 , vol. 65, p. 446 - 446
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Gmelin Handbook: Os: MVol., 29, page 55 - 57
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Bornemann, F.
Dissert. Danzig T. H. 1910, S. 46
Colton, R.; Farthing, R. H.
Australian Journal of Chemistry, 1968 , vol. 21, p. 589 - 593
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Gmelin Handbook: Os: SVol.1, 3.4.5, page 125 - 126
byproducts: Cl2; by heating at 160-170°C; formed cubic OsCl4;
参考文献
Burns, R. C.; O'Donnell, T. A.
Inorganic Chemistry, 1979 , vol. 18, p. 3081 - 3086
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Gmelin Handbook: Os: SVol.1, 3.4.3, page 124 - 125
in neat (no solvent) Os is heated in a stream of Cl2 (1050 °C, porcelain tube); the subliming chlorides are rapidly cooled using a platinum condenser;; chem. anal.;;
参考文献
Ruff, O.; Bornemann, F.
Z. Anorg. Chem., 1910 , vol. 65, p. 450 - 501
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Gmelin Handbook: Os: MVol., 28, page 53 - 55
Dillamore, I. M.; Edwads, D. A.
J. Inorg. Chem., 1969 , vol. 31, p. 2427 - 2430
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Gmelin Handbook: Os: SVol.1, 1.4, page 18 - 19
