Elko Chemical Co.
Patent: US1753754 , 1930 ;
C. I, 1930 , p. 3820
Full Text Show Details
Elko Chemical Co.
Patent: US1788959 , 1931 ;
C. I, 1931 , p. 1806
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 122, page 1791 - 1793
in neat (no solvent) byproducts: NOCl, NO2Cl; Irradiation (UV/VIS); passing dry N2O4 over the surface of freshly distd. PCl3 cooled at -40 °C and under irradiation with UV light; absortion under formation of a dark red liq.; expelling NO, N2O3, NOCl, NO2Cl;; isolation of liquid products by fractionation; liquid phase containing POCl3, P2O3Cl4 and P4O4Cl10; yield of P2O3Cl4 25 percent, P4O4Cl10 3 percent;;
参考文献
P: MVol.C, 184, page 424 - 427
Diss. Muenchen 1959, S. 1/98
→
反应条件
in chloroform react. of a soln. of WCl6 in CHCl3 with P2O5;;
