water in not given
Kinetics; hydrolysis; more than 30 fold excess of H2O (compared with S2Cl2);;
参考文献
Rao, B. S.
Proceedings - Indian Academy of Sciences, Section A, 1939 , vol. 10, p. 423 - 448
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Gmelin Handbook: S: MVol.B3, 112, page 1770 - 1773
sodium hydroxide; water in Petroleum ether
byproducts: polythionic acids, HCl; shaking soln. (H2O free of air/aq. NaCl) for 2h; alkaline hydrolysis; main products: sulfur and S2O3(2-); discussion of yields;;
参考文献
Goehring, M.; Stamm, H.; Feldmann, U.
Z. Anorg. Chem., 1942 , vol. 250, p. 56 - 71
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Gmelin Handbook: S: MVol.B3, 112, page 1770 - 1773
water in water
byproducts: polythionic acids; storage for longer period of time (room temp./CO2 atm./exclusion of air/75 or 500 fold excess of water); reaction discussed;;
参考文献
Noack, E.
Z. Anorg. Chem., 1925 , vol. 146, p. 239 - 262
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Gmelin Handbook: S: MVol.B3, 112, page 1770 - 1773
sodium hydroxide; water; cadmium (II) chloride in tetrachloromethane
byproducts: CdS; alkaline hydrolysis; shaking (1-2 min) of S2Cl2 (10E4 -10E3 mol/in CCl4) with excess aq. NaOH (very dild.) in presence of CdCl2; further byproduct: Sμ; mechanism (depending on concns. of educts and temps.) discussed;;
参考文献
Rao, B. S.
Proceedings - Indian Academy of Sciences, Section A, 1939 , vol. 10, p. 423 - 448
Full Text View citing articles Show Details
Gmelin Handbook: S: MVol.B3, 112, page 1770 - 1773
hydrogenchloride; water in Petroleum ether
byproducts: polythionic acids; hydrolysis on shaking (2h) mixture of S2Cl2 (in petroleum ether), aq. Na2S2O3 and aq. HCl; dependence on concn. of Na2S2O3 discussed;;
参考文献
Goehring, M.; Stamm, H.; Feldmann, U.
Z. Anorg. Chem., 1942 , vol. 250, p. 56 - 71
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Gmelin Handbook: S: MVol.B3, 112, page 1770 - 1773
Schenk, P. W.; Steudel, R.; Toepert, M.
Z. Naturforsch. b, 1964 , vol. 19, p. 535 - 536
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Gmelin Handbook: S: SVol.3, 1.10.1, page 17 - 21
in diethyl ether
S2Cl2 dild. in ether; introduction of dry NH3 (cooling); after 0.5h first brown mixture becomes orange;; pptn.; extraction (ether); evapn.; benzene or CS2 as solvent reduce yield;;
参考文献
Valkenburgh, H. B. van; Bailar, J. C.
Journal of the American Chemical Society, 1925 , vol. 47, p. 2134 - 2137
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Gmelin Handbook: S: MVol.B3, 4, page 1537 - 1540
